A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh2 and tBuOK
Publication type: Journal Article
Publication date: 2021-08-17
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
34524311
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A general method for the demethylation, debenzylation, and deallylation of aryl ethers using HPPh2 and tBuOK is reported. The reaction features mild and metal-free reaction conditions, broad substrate scope, good functional group compatibility, and high chemical selectivity towards aryl ethers over aliphatic structures. Notably, this approach is competent to selectively deprotect the allyl or benzyl group, making it a general and practical method in organic synthesis.
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GOST
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Pan W. et al. A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh2 and tBuOK // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 35. pp. 7633-7640.
GOST all authors (up to 50)
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Pan W., Li C., Zhu H., Li F., Li T., Zhao W. A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh2 and tBuOK // Organic and Biomolecular Chemistry. 2021. Vol. 19. No. 35. pp. 7633-7640.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d1ob01286j
UR - https://xlink.rsc.org/?DOI=D1OB01286J
TI - A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh2 and tBuOK
T2 - Organic and Biomolecular Chemistry
AU - Pan, Wenjing
AU - Li, Chenchen
AU - Zhu, Haoyin
AU - Li, Fangfang
AU - Li, Tao
AU - Zhao, Wanxiang
PY - 2021
DA - 2021/08/17
PB - Royal Society of Chemistry (RSC)
SP - 7633-7640
IS - 35
VL - 19
PMID - 34524311
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Pan,
author = {Wenjing Pan and Chenchen Li and Haoyin Zhu and Fangfang Li and Tao Li and Wanxiang Zhao},
title = {A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh2 and tBuOK},
journal = {Organic and Biomolecular Chemistry},
year = {2021},
volume = {19},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://xlink.rsc.org/?DOI=D1OB01286J},
number = {35},
pages = {7633--7640},
doi = {10.1039/d1ob01286j}
}
Cite this
MLA
Copy
Pan, Wenjing, et al. “A mild and practical method for deprotection of aryl methyl/benzyl/allyl ethers with HPPh2 and tBuOK.” Organic and Biomolecular Chemistry, vol. 19, no. 35, Aug. 2021, pp. 7633-7640. https://xlink.rsc.org/?DOI=D1OB01286J.