Transition metal-free and solvent-free calcium carbide promotes the formation of β-keto sulfoxide from acyl chloride and DMSO
Pei-Wen Yang
1, 2, 3, 4, 5, 6
,
Xin-Xin Liu
1, 2, 3, 4, 5, 6
,
Xue Qiang Li
1
,
Li Xue-qiang
1, 2, 3, 4, 5, 6
,
Mengxue Wei
1, 2, 3, 4, 5, 6
2
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering
3
Ningxia Engineering Research Center for Natural Medicine
4
National Demonstration Center for Experimental Chemistry Education
5
College of Chemistry and Chemical Engineering
Тип публикации: Journal Article
Дата публикации: 2021-04-07
scimago Q1
wos Q1
БС1
SJR: 1.068
CiteScore: 8.2
Impact factor: 4.7
ISSN: 20524110, 20524129
Organic Chemistry
Краткое описание
Inexpensive and readily available calcium carbide (CaC2) has been developed as a promoter for the transition metal-free, solvent-free and one-pot conversion of acid chlorides and dimethyl sulfoxide (DMSO) to the corresponding β-keto sulfoxide. Four drug molecules were successfully converted to their β-keto sulfoxides using this method, emphasising its potential utility in medicinal chemistry.
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Yang P. et al. Transition metal-free and solvent-free calcium carbide promotes the formation of β-keto sulfoxide from acyl chloride and DMSO // Organic Chemistry Frontiers. 2021. Vol. 8. No. 12. pp. 2914-2918.
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Yang P., Liu X., Li X. Q., Xue-qiang L., Wei M. Transition metal-free and solvent-free calcium carbide promotes the formation of β-keto sulfoxide from acyl chloride and DMSO // Organic Chemistry Frontiers. 2021. Vol. 8. No. 12. pp. 2914-2918.
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TY - JOUR
DO - 10.1039/d1qo00147g
UR - https://xlink.rsc.org/?DOI=D1QO00147G
TI - Transition metal-free and solvent-free calcium carbide promotes the formation of β-keto sulfoxide from acyl chloride and DMSO
T2 - Organic Chemistry Frontiers
AU - Yang, Pei-Wen
AU - Liu, Xin-Xin
AU - Li, Xue Qiang
AU - Xue-qiang, Li
AU - Wei, Mengxue
PY - 2021
DA - 2021/04/07
PB - Royal Society of Chemistry (RSC)
SP - 2914-2918
IS - 12
VL - 8
SN - 2052-4110
SN - 2052-4129
ER -
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@article{2021_Yang,
author = {Pei-Wen Yang and Xin-Xin Liu and Xue Qiang Li and Li Xue-qiang and Mengxue Wei},
title = {Transition metal-free and solvent-free calcium carbide promotes the formation of β-keto sulfoxide from acyl chloride and DMSO},
journal = {Organic Chemistry Frontiers},
year = {2021},
volume = {8},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=D1QO00147G},
number = {12},
pages = {2914--2918},
doi = {10.1039/d1qo00147g}
}
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MLA
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Yang, Pei-Wen, et al. “Transition metal-free and solvent-free calcium carbide promotes the formation of β-keto sulfoxide from acyl chloride and DMSO.” Organic Chemistry Frontiers, vol. 8, no. 12, Apr. 2021, pp. 2914-2918. https://xlink.rsc.org/?DOI=D1QO00147G.