Physical Chemistry Chemical Physics, volume 24, issue 42, pages 26083-26093
The role of terphenyl-containing carboxylic acid in the oligomerization of aryl vinyl ketone
Bondarenko G.N.
1
,
Karpov O N
1
,
Shandryuk G A
1
,
Finko A V
1, 2
,
Derikov Y I
1
,
Mikhalyonok S G
3
,
Bezborodov V S
3
,
Publication type: Journal Article
Publication date: 2022-10-21
Journal:
Physical Chemistry Chemical Physics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 3.3
ISSN: 14639076, 14639084
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The molecular structure of 8-((4''-((1R,4S)-4-butylcyclohexyl)-2'-chloro-[1,1',4',1''-terphenyl]-4-yl)oxy)oct-1-en-3-one (TERPh-VK) and 6-((4''-((1R,4S)-4-butylcyclohexyl)-2'-chloro-[1,1':4',1''-terphenyl]-4-yl)oxy) hexanoic acid (TERPh-COOH) is analyzed by FTIR spectroscopy. Vinyl ketone isolated from solution forms a thermodynamically unstable cis conformation due to probable peculiarities of the crystal structure formation. The heating of this substance above 100 °C results in the cis-trans transformation with the simultaneous opening of the vinyl double bond. The mixing of the above terphenyls in solution followed by the isolation of the solid product results in the formation of the TERPh-VK/TERPH-COOH associated species due to the H-bonding between ketone and carboxylic groups. The thermal transformation of the H-bond associated species resulted in the formation of the oligo (TERPh-VK)/TERPh-COOH associated species.
Citations by journals
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Polymers
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Polymers
1 publication, 100%
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Citations by publishers
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 100%
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Bondarenko G. et al. The role of terphenyl-containing carboxylic acid in the oligomerization of aryl vinyl ketone // Physical Chemistry Chemical Physics. 2022. Vol. 24. No. 42. pp. 26083-26093.
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Bondarenko G., Karpov O. N., Shandryuk G. A., Finko A. V., Derikov Y. I., Mikhalyonok S. G., Bezborodov V. S., Talroze R. The role of terphenyl-containing carboxylic acid in the oligomerization of aryl vinyl ketone // Physical Chemistry Chemical Physics. 2022. Vol. 24. No. 42. pp. 26083-26093.
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TY - JOUR
DO - 10.1039/d2cp03187f
UR - https://doi.org/10.1039%2Fd2cp03187f
TI - The role of terphenyl-containing carboxylic acid in the oligomerization of aryl vinyl ketone
T2 - Physical Chemistry Chemical Physics
AU - Bondarenko, G.N.
AU - Karpov, O N
AU - Shandryuk, G A
AU - Finko, A V
AU - Derikov, Y I
AU - Mikhalyonok, S G
AU - Bezborodov, V S
AU - Talroze, R.V.
PY - 2022
DA - 2022/10/21 00:00:00
PB - Royal Society of Chemistry (RSC)
SP - 26083-26093
IS - 42
VL - 24
SN - 1463-9076
SN - 1463-9084
ER -
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@article{2022_Bondarenko,
author = {G.N. Bondarenko and O N Karpov and G A Shandryuk and A V Finko and Y I Derikov and S G Mikhalyonok and V S Bezborodov and R.V. Talroze},
title = {The role of terphenyl-containing carboxylic acid in the oligomerization of aryl vinyl ketone},
journal = {Physical Chemistry Chemical Physics},
year = {2022},
volume = {24},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039%2Fd2cp03187f},
number = {42},
pages = {26083--26093},
doi = {10.1039/d2cp03187f}
}
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Bondarenko, G.N., et al. “The role of terphenyl-containing carboxylic acid in the oligomerization of aryl vinyl ketone.” Physical Chemistry Chemical Physics, vol. 24, no. 42, Oct. 2022, pp. 26083-26093. https://doi.org/10.1039%2Fd2cp03187f.