Domino assembly of dithiocarbamates via Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors
Тип публикации: Journal Article
Дата публикации: 2022-07-01
SCImago Q2
WOS Q2
БС1
SJR: 0.475
CiteScore: 4.8
Impact factor: 2.8
ISSN: 14770520, 14770539
PubMed ID:
35815554
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
An efficient domino approach to assemble benzoxazoles and anthranilamides bearing dithiocarbamate moieties has been developed. The proposed route represents a Cu-catalyzed three-component reaction between readily available 5-iodo-1,2,3-triazoles, amines, and CS2. The cascade transformation is based on a denitrogenative coupling of in situ formed dithiocarbamic acids with diazo intermediates, generated via annulation-triggered triazole ring-opening. This method is applicable to nucleophilic secondary amines and features good functional group compatibility.
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Kotovshchikov Y. N. et al. Domino assembly of dithiocarbamates via Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors // Organic and Biomolecular Chemistry. 2022. Vol. 20. No. 29. pp. 5764-5770.
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Kotovshchikov Y. N., Sultanov R. H., Latyshev G. V., Lukashev N. V., Beletskaya I. P. Domino assembly of dithiocarbamates via Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors // Organic and Biomolecular Chemistry. 2022. Vol. 20. No. 29. pp. 5764-5770.
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TY - JOUR
DO - 10.1039/d2ob00909a
UR - https://xlink.rsc.org/?DOI=D2OB00909A
TI - Domino assembly of dithiocarbamates via Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors
T2 - Organic and Biomolecular Chemistry
AU - Kotovshchikov, Yury N
AU - Sultanov, Rinat H
AU - Latyshev, Gennadij V
AU - Lukashev, Nikolay V
AU - Beletskaya, Irina P.
PY - 2022
DA - 2022/07/01
PB - Royal Society of Chemistry (RSC)
SP - 5764-5770
IS - 29
VL - 20
PMID - 35815554
SN - 1477-0520
SN - 1477-0539
ER -
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@article{2022_Kotovshchikov,
author = {Yury N Kotovshchikov and Rinat H Sultanov and Gennadij V Latyshev and Nikolay V Lukashev and Irina P. Beletskaya},
title = {Domino assembly of dithiocarbamates via Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors},
journal = {Organic and Biomolecular Chemistry},
year = {2022},
volume = {20},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=D2OB00909A},
number = {29},
pages = {5764--5770},
doi = {10.1039/d2ob00909a}
}
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MLA
Скопировать
Kotovshchikov, Yury N., et al. “Domino assembly of dithiocarbamates via Cu-catalyzed denitrogenative thiolation of iodotriazole-based diazo precursors.” Organic and Biomolecular Chemistry, vol. 20, no. 29, Jul. 2022, pp. 5764-5770. https://xlink.rsc.org/?DOI=D2OB00909A.
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