Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization
Publication type: Journal Article
Publication date: 2022-03-31
scimago Q1
wos Q2
SJR: 0.842
CiteScore: 7.6
Impact factor: 3.9
ISSN: 17599954, 17599962
Organic Chemistry
Biochemistry
Polymers and Plastics
Bioengineering
Abstract
Sulfur-functionalized poly(α-olefin) is an excellent building block for constructing topological and functional polymers but it has been utilized as an amorphous material up to now. Through a fundamental structure/property study that reveals the intriguing effects of the steric hindrance/electronic properties of the monomer, the spacer length between the sulfur atom and olefin group, and the stereoselectivity of the polymerization process on the crystalline performance of sulfur-functionalized poly(α-olefin), the first crystalline sulfur-functionalized poly(α-olefin) is reported. Combined with organoborate, an N-heterocyclic carbene ligated scandium trialkyl complex catalyzed monomers to produce a series of syndiotactic sulfur-functionalized poly(α-olefin)s (rrrr up to 0.95) which formed crystalline materials with a Tm of up to 91 °C.
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Total citations:
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Citations from 2024:
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(83.33%)
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Liu Z. X., Xu T. Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization // Polymer Chemistry. 2022. Vol. 13. No. 17. pp. 2477-2483.
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Liu Z. X., Xu T. Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization // Polymer Chemistry. 2022. Vol. 13. No. 17. pp. 2477-2483.
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RIS
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TY - JOUR
DO - 10.1039/d2py00315e
UR - https://xlink.rsc.org/?DOI=D2PY00315E
TI - Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization
T2 - Polymer Chemistry
AU - Liu, Zhao Xuan
AU - Xu, Tie‐Qi
PY - 2022
DA - 2022/03/31
PB - Royal Society of Chemistry (RSC)
SP - 2477-2483
IS - 17
VL - 13
SN - 1759-9954
SN - 1759-9962
ER -
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BibTex (up to 50 authors)
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@article{2022_Liu,
author = {Zhao Xuan Liu and Tie‐Qi Xu},
title = {Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization},
journal = {Polymer Chemistry},
year = {2022},
volume = {13},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D2PY00315E},
number = {17},
pages = {2477--2483},
doi = {10.1039/d2py00315e}
}
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MLA
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Liu, Zhao Xuan, and Tie‐Qi Xu. “Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization.” Polymer Chemistry, vol. 13, no. 17, Mar. 2022, pp. 2477-2483. https://xlink.rsc.org/?DOI=D2PY00315E.