Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers
Publication type: Journal Article
Publication date: 2022-06-18
scimago Q1
wos Q2
SJR: 0.842
CiteScore: 7.6
Impact factor: 3.9
ISSN: 17599954, 17599962
Organic Chemistry
Biochemistry
Polymers and Plastics
Bioengineering
Abstract
Several binuclear vanadium complexes were synthesized and investigated as catalysts for ethylene (co)polymerization. Under the activation of Et2AlCl, the binuclear vanadium complexes exhibited higher activities than the mononuclear analogues in ethylene polymerization. Also, the binuclear complexes showed moderate activity in the copolymerization with polar vinyl monomers such as 6-chlorohex-1-ene, 10-undecen-1-ol and methyl 10-undecenoate. In the copolymerization with methyl acrylate, the binuclear catalysts exhibited good tolerance to the polar group with activity up to 529 kg molV−1 h−1. But only a pure polyethylene product was obtained according to the 1H NMR spectrum.
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Citations from 2024:
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GOST
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Nie J. et al. Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers // Polymer Chemistry. 2022. Vol. 13. No. 26. pp. 3876-3881.
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Nie J., Ren F., Li Z., Tian K., Zou H., Hou X. Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers // Polymer Chemistry. 2022. Vol. 13. No. 26. pp. 3876-3881.
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RIS
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TY - JOUR
DO - 10.1039/d2py00402j
UR - https://xlink.rsc.org/?DOI=D2PY00402J
TI - Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers
T2 - Polymer Chemistry
AU - Nie, Jinxin
AU - Ren, Feiyang
AU - Li, Zhen
AU - Tian, Kun
AU - Zou, Hui
AU - Hou, Xiaohua
PY - 2022
DA - 2022/06/18
PB - Royal Society of Chemistry (RSC)
SP - 3876-3881
IS - 26
VL - 13
SN - 1759-9954
SN - 1759-9962
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Nie,
author = {Jinxin Nie and Feiyang Ren and Zhen Li and Kun Tian and Hui Zou and Xiaohua Hou},
title = {Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers},
journal = {Polymer Chemistry},
year = {2022},
volume = {13},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=D2PY00402J},
number = {26},
pages = {3876--3881},
doi = {10.1039/d2py00402j}
}
Cite this
MLA
Copy
Nie, Jinxin, et al. “Design and synthesis of binuclear vanadium catalysts for copolymerization of ethylene and polar monomers.” Polymer Chemistry, vol. 13, no. 26, Jun. 2022, pp. 3876-3881. https://xlink.rsc.org/?DOI=D2PY00402J.