volume 26 issue 3 pages 277-285

Upconversion luminescence and temperature measurement performance of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors

Publication typeJournal Article
Publication date2024-01-01
scimago Q2
wos Q2
SJR0.520
CiteScore5.2
Impact factor2.6
ISSN14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
New series of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors have been prepared by a conventional solid state reaction method. A powder XRD study has revealed that all the synthesized tungstates are isostructural and crystallize in the trigonal crystal system (sp. gr. R32, Z = 3). Upconversion luminescence in the 460–850 nm spectral range, associated with transitions in Ho3+ or Tm3+ ions, has been detected under 980 nm laser diode excitation. The optimal Ho3+/Yb3+ and Tm3+/Yb3+ ratios have been determined. Possible mechanisms of energy transfer between lanthanide ions have been discussed. The luminescence characteristics of the representative samples, Na5Rb7Sc1.925Yb0.045Ho0.03(WO4)9 and Na5Rb7Sc1.9Yb0.09Tm0.01(WO4)9, have been studied at 298–498 K to evaluate their temperature measurement performance. The calculated values of the absolute and relative sensitivities indicate that the studied tungstates are promising phosphors for non-contact thermometry.
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Lipina O. A. et al. Upconversion luminescence and temperature measurement performance of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors // CrystEngComm. 2024. Vol. 26. No. 3. pp. 277-285.
GOST all authors (up to 50) Copy
Lipina O. A., Baklanova Y. V., Spiridonova T. S., Khaikina E. Upconversion luminescence and temperature measurement performance of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors // CrystEngComm. 2024. Vol. 26. No. 3. pp. 277-285.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/d3ce01020a
UR - https://xlink.rsc.org/?DOI=D3CE01020A
TI - Upconversion luminescence and temperature measurement performance of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors
T2 - CrystEngComm
AU - Lipina, Olga A
AU - Baklanova, Yana V
AU - Spiridonova, Tatyana S.
AU - Khaikina, Elena
PY - 2024
DA - 2024/01/01
PB - Royal Society of Chemistry (RSC)
SP - 277-285
IS - 3
VL - 26
SN - 1466-8033
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Lipina,
author = {Olga A Lipina and Yana V Baklanova and Tatyana S. Spiridonova and Elena Khaikina},
title = {Upconversion luminescence and temperature measurement performance of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors},
journal = {CrystEngComm},
year = {2024},
volume = {26},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D3CE01020A},
number = {3},
pages = {277--285},
doi = {10.1039/d3ce01020a}
}
MLA
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MLA Copy
Lipina, Olga A., et al. “Upconversion luminescence and temperature measurement performance of Ho3+/Yb3+ and Tm3+/Yb3+ codoped Na5Rb7Sc2(WO4)9 phosphors.” CrystEngComm, vol. 26, no. 3, Jan. 2024, pp. 277-285. https://xlink.rsc.org/?DOI=D3CE01020A.