Divergent methods for polyester and polycarbonate depolymerization with a cobalt catalyst
Kai D. Knight
1
,
Megan E Fieser
1, 2
Publication type: Journal Article
Publication date: 2024-01-01
scimago Q1
wos Q1
SJR: 1.276
CiteScore: 9.9
Impact factor: 6.4
ISSN: 20521545, 20521553
Inorganic Chemistry
Abstract
A pyridine diimine cobalt catalyst series is used for the cyclodepolymerization (CDP) of several different polyesters and polycarbonates. In the presence of isopropanol, a wide range of polymers can undergo solvolytic depolymerization. CDP of poly(propylene carbonate) revealed an unzip back-biting or random scission mechanism, depending on what conditions were used. The first example of a method capable of solvolysis and CDP on a polymer mixture in the same pot is identified.
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Metrics
11
Total citations:
11
Citations from 2025:
8
(72.73%)
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MLA
Cite this
GOST
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Knight K. D., Fieser M. E. Divergent methods for polyester and polycarbonate depolymerization with a cobalt catalyst // Inorganic Chemistry Frontiers. 2024. Vol. 11. No. 1. pp. 298-309.
GOST all authors (up to 50)
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Knight K. D., Fieser M. E. Divergent methods for polyester and polycarbonate depolymerization with a cobalt catalyst // Inorganic Chemistry Frontiers. 2024. Vol. 11. No. 1. pp. 298-309.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d3qi01833d
UR - https://xlink.rsc.org/?DOI=D3QI01833D
TI - Divergent methods for polyester and polycarbonate depolymerization with a cobalt catalyst
T2 - Inorganic Chemistry Frontiers
AU - Knight, Kai D.
AU - Fieser, Megan E
PY - 2024
DA - 2024/01/01
PB - Royal Society of Chemistry (RSC)
SP - 298-309
IS - 1
VL - 11
SN - 2052-1545
SN - 2052-1553
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2024_Knight,
author = {Kai D. Knight and Megan E Fieser},
title = {Divergent methods for polyester and polycarbonate depolymerization with a cobalt catalyst},
journal = {Inorganic Chemistry Frontiers},
year = {2024},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D3QI01833D},
number = {1},
pages = {298--309},
doi = {10.1039/d3qi01833d}
}
Cite this
MLA
Copy
Knight, Kai D., et al. “Divergent methods for polyester and polycarbonate depolymerization with a cobalt catalyst.” Inorganic Chemistry Frontiers, vol. 11, no. 1, Jan. 2024, pp. 298-309. https://xlink.rsc.org/?DOI=D3QI01833D.
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