Aromatization-driven cascade [1,5]-hydride transfer/cyclization for synthesis of spirochromanes
Publication type: Journal Article
Publication date: 2023-03-08
scimago Q1
wos Q1
SJR: 1.068
CiteScore: 8.2
Impact factor: 4.7
ISSN: 20524110, 20524129
Organic Chemistry
Abstract
An aromatization-driven hydride transfer-involved α-C(sp3)–H bond functionalization of the oxygen atom was developed. In this transformation, easily prepared p-quinone methides were applied as aromatic precursors to initiate a [1,5]-hydride transfer/cyclization reaction for generating cyclohexadienone fused spirochromanes. A variety of spirochromanes, including privileged molecules with two spirochromane moieties linked by an alkenyl or a phenyl group, were obtained in high efficiency. In addition, the derivatizations of products were conducted to further enrich the diversity of the structure.
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10
Total citations:
10
Citations from 2025:
5
(50%)
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Cao L. et al. Aromatization-driven cascade [1,5]-hydride transfer/cyclization for synthesis of spirochromanes // Organic Chemistry Frontiers. 2023. Vol. 10. No. 7. pp. 1796-1802.
GOST all authors (up to 50)
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Cao L., Hu F., Dong J., Zhang X., Li S. Aromatization-driven cascade [1,5]-hydride transfer/cyclization for synthesis of spirochromanes // Organic Chemistry Frontiers. 2023. Vol. 10. No. 7. pp. 1796-1802.
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RIS
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TY - JOUR
DO - 10.1039/d3qo00035d
UR - https://xlink.rsc.org/?DOI=D3QO00035D
TI - Aromatization-driven cascade [1,5]-hydride transfer/cyclization for synthesis of spirochromanes
T2 - Organic Chemistry Frontiers
AU - Cao, Lianyi
AU - Hu, Fangzhi
AU - Dong, Jiacheng
AU - Zhang, Xiaomei
AU - Li, Shuai-Shuai
PY - 2023
DA - 2023/03/08
PB - Royal Society of Chemistry (RSC)
SP - 1796-1802
IS - 7
VL - 10
SN - 2052-4110
SN - 2052-4129
ER -
Cite this
BibTex (up to 50 authors)
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@article{2023_Cao,
author = {Lianyi Cao and Fangzhi Hu and Jiacheng Dong and Xiaomei Zhang and Shuai-Shuai Li},
title = {Aromatization-driven cascade [1,5]-hydride transfer/cyclization for synthesis of spirochromanes},
journal = {Organic Chemistry Frontiers},
year = {2023},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D3QO00035D},
number = {7},
pages = {1796--1802},
doi = {10.1039/d3qo00035d}
}
Cite this
MLA
Copy
Cao, Lianyi, et al. “Aromatization-driven cascade [1,5]-hydride transfer/cyclization for synthesis of spirochromanes.” Organic Chemistry Frontiers, vol. 10, no. 7, Mar. 2023, pp. 1796-1802. https://xlink.rsc.org/?DOI=D3QO00035D.