Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction
Publication type: Journal Article
Publication date: 2024-02-20
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
38441230
Inorganic Chemistry
Abstract
Three mononuclear Ge(IV) compounds, [(C6H5)2Ge(C13H8N2O4)] (1), [(C6H5)2Ge(C14H10N2O5)] (2), and [(C6H5)2Ge(C14H11NO3)] (3), have been synthesized by the reaction of pro-ligands H2L1 (C13H10N2O4), H2L2 (C14H12N2O5), and H2L3 (C14H13NO3) with (C6H5)2GeCl2 in the presence of triethylamine. All compounds were characterized by FT-IR spectroscopy and NMR spectroscopy. Single crystal X-ray diffraction analysis shows that the germanium(IV) atom exhibits a five-coordinated geometry in compounds 1 and 2. All compounds were screened as Lewis acid catalysts in the [3 + 2] cycloaddition reaction between sodium azide and various nitriles. The reactions resulted in the formation of 5-substituted 1H-tetrazoles with yields of up to 96%. Based on the experimental findings and DFT calculations, a plausible mechanism is proposed for the [3 + 2] cycloaddition reaction.
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Total citations:
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Citations from 2025:
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(46.67%)
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Basu D. et al. Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction // Dalton Transactions. 2024. Vol. 53. No. 12. pp. 5648-5657.
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Basu D., Ghosh B., Srivastava D., Patra N., Nayek H. P. Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction // Dalton Transactions. 2024. Vol. 53. No. 12. pp. 5648-5657.
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RIS
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TY - JOUR
DO - 10.1039/d4dt00239c
UR - https://xlink.rsc.org/?DOI=D4DT00239C
TI - Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction
T2 - Dalton Transactions
AU - Basu, Debayan
AU - Ghosh, Barshali
AU - Srivastava, Diship
AU - Patra, N.
AU - Nayek, Hari Pada
PY - 2024
DA - 2024/02/20
PB - Royal Society of Chemistry (RSC)
SP - 5648-5657
IS - 12
VL - 53
PMID - 38441230
SN - 1477-9226
SN - 1477-9234
ER -
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BibTex (up to 50 authors)
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@article{2024_Basu,
author = {Debayan Basu and Barshali Ghosh and Diship Srivastava and N. Patra and Hari Pada Nayek},
title = {Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction},
journal = {Dalton Transactions},
year = {2024},
volume = {53},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=D4DT00239C},
number = {12},
pages = {5648--5657},
doi = {10.1039/d4dt00239c}
}
Cite this
MLA
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Basu, Debayan, et al. “Mononuclear Organogermanium(IV) Catalysts for [3+2] Cycloaddition Reaction.” Dalton Transactions, vol. 53, no. 12, Feb. 2024, pp. 5648-5657. https://xlink.rsc.org/?DOI=D4DT00239C.