Phenoxazinyl Zn(ii ) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii ) complex
Publication type: Journal Article
Publication date: 2024-04-02
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
38563205
Inorganic Chemistry
Abstract
Aerobic reaction between the pyridine-2-carboxamide-2-aminophenol N3O ligand (H3L1) and Zn(ClO4)2·6H2O in CH3CN affords an N3 phenoxazinylate coordinated Zn(II) complex; its diradical electronic structure [ZnII{(L1*)˙−}2] has been elucidated from redox, spectroscopic (UV-VIS and EPR), and magnetic measurements and DFT calculations. Isolation and characterization of the metal-assisted redox-driven modified N3 ligand as a radical cation (H2L1*)˙+ and its Ni(II)-diradical complex [NiII{(L1*)˙−}2] have also been achieved.
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Total citations:
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Citations from 2025:
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(71.43%)
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Mukhopadhyay N. et al. Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii) complex // Dalton Transactions. 2024. Vol. 53. No. 15. pp. 6515-6519.
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Mukhopadhyay N., Sengupta A., Lloret F., Mukherjee R. Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii) complex // Dalton Transactions. 2024. Vol. 53. No. 15. pp. 6515-6519.
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TY - JOUR
DO - 10.1039/d4dt00374h
UR - https://xlink.rsc.org/?DOI=D4DT00374H
TI - Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii) complex
T2 - Dalton Transactions
AU - Mukhopadhyay, Narottam
AU - Sengupta, Arunava
AU - Lloret, Francesc
AU - Mukherjee, R.
PY - 2024
DA - 2024/04/02
PB - Royal Society of Chemistry (RSC)
SP - 6515-6519
IS - 15
VL - 53
PMID - 38563205
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2024_Mukhopadhyay,
author = {Narottam Mukhopadhyay and Arunava Sengupta and Francesc Lloret and R. Mukherjee},
title = {Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii) complex},
journal = {Dalton Transactions},
year = {2024},
volume = {53},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=D4DT00374H},
number = {15},
pages = {6515--6519},
doi = {10.1039/d4dt00374h}
}
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MLA
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Mukhopadhyay, Narottam, et al. “Phenoxazinyl Zn(ii) diradical complex formed via redox-driven cyclization of a 2-aminophenol-based N3O ligand. Isolation of the modified N3 ligand radical and its Ni(ii) complex.” Dalton Transactions, vol. 53, no. 15, Apr. 2024, pp. 6515-6519. https://xlink.rsc.org/?DOI=D4DT00374H.