X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 +? catalysts for methanol oxidation
Publication type: Journal Article
Publication date: 1994-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 09565000, 13645455
Physical and Theoretical Chemistry
Abstract
An X-ray photoelectron spectroscopy (XPS), temperature-programmed desorption (TPD) and reduction (TPR) study of LaNiO3 and La2NiO4+δ perovskites has been carried out. The existence of at least two different forms of oxygen in these compounds is shown by both oxygen reactivity (TPD and TPR) and XPS characterisation. XP spectra have also revealed a surface enrichment in lanthanum and oxygen. TPR profiles have shown a reduction of LaNiO3 through the formation of La2Ni2O5 as an intermediate compound. Above 450 °C, LaNiO3 and intergrowth nickelates (La2NiO4 and La2NiO4 +δ) undergo a final reduction to metallic Ni and La2O3. Between 200 and 400 °C all three compounds exhibit a high catalytic activity in the total catalytic oxidation of methanol.
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Total citations:
66
Citations from 2025:
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(3.03%)
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Choisnet J. et al. X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 +? catalysts for methanol oxidation // Journal of the Chemical Society Faraday Transactions. 1994. Vol. 90. No. 13. p. 1987.
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Choisnet J., Abadzhieva N., Stefanov P., Klissurski D., Bassat J., Jean Marc B., Rives V., Minchev L. X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 +? catalysts for methanol oxidation // Journal of the Chemical Society Faraday Transactions. 1994. Vol. 90. No. 13. p. 1987.
Cite this
RIS
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TY - JOUR
DO - 10.1039/ft9949001987
UR - https://doi.org/10.1039/ft9949001987
TI - X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 +? catalysts for methanol oxidation
T2 - Journal of the Chemical Society Faraday Transactions
AU - Choisnet, Jacques
AU - Abadzhieva, Navena
AU - Stefanov, Plamen
AU - Klissurski, Dimitar
AU - Bassat, Jean-Marc
AU - Jean Marc, Bassat
AU - Rives, V.
AU - Minchev, Lev
PY - 1994
DA - 1994/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1987
IS - 13
VL - 90
SN - 0956-5000
SN - 1364-5455
ER -
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@article{1994_Choisnet,
author = {Jacques Choisnet and Navena Abadzhieva and Plamen Stefanov and Dimitar Klissurski and Jean-Marc Bassat and Bassat Jean Marc and V. Rives and Lev Minchev},
title = {X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 +? catalysts for methanol oxidation},
journal = {Journal of the Chemical Society Faraday Transactions},
year = {1994},
volume = {90},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/ft9949001987},
number = {13},
pages = {1987},
doi = {10.1039/ft9949001987}
}
Cite this
MLA
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Choisnet, Jacques, et al. “X-ray photoelectron spectroscopy, temperature-programmed desorption and temperature-programmed reduction study of LaNiO3 and La2NiO4 +? catalysts for methanol oxidation.” Journal of the Chemical Society Faraday Transactions, vol. 90, no. 13, Jan. 1994, p. 1987. https://doi.org/10.1039/ft9949001987.