Journal of the Chemical Society C Organic, pages 869
Partially fluorinated heterocyclic compounds. Part III. The preparation of 4,5,6,7-tetrafluorobenzo[b]furan
Publication type: Journal Article
Publication date: 1967-01-01
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ISSN: 00224952
Organic Chemistry
Abstract
4,5,6,7-Tetrafluoro-2,3-dihydrobenzo[b]furan-3-one has been prepared by the cyclisation and decarboxylation of ethyl 6-ethoxycarbonyl-2,3,4,5-tetrafluorophenoxyacetate and by the reaction of 2,3,4,5-tetrafluorophenoxyacetic acid with butyl-lithium followed by carbonation. Reduction and dehydration of the benzo[b]furan-3-one gave 4,5,6,7-tetrafluorobenzo[b]furan. The attempted electrophilic cyclisation reactions of 2,3,4,5-tetrafluorophenoxy-acetic acid, -acetyl chloride, and -acetaldehyde diethyl acetal are reported.
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Brooke G., Furniss B. S. Partially fluorinated heterocyclic compounds. Part III. The preparation of 4,5,6,7-tetrafluorobenzo[b]furan // Journal of the Chemical Society C Organic. 1967. p. 869.
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Brooke G., Furniss B. S. Partially fluorinated heterocyclic compounds. Part III. The preparation of 4,5,6,7-tetrafluorobenzo[b]furan // Journal of the Chemical Society C Organic. 1967. p. 869.
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TY - JOUR
DO - 10.1039/j39670000869
UR - https://doi.org/10.1039/j39670000869
TI - Partially fluorinated heterocyclic compounds. Part III. The preparation of 4,5,6,7-tetrafluorobenzo[b]furan
T2 - Journal of the Chemical Society C Organic
AU - Brooke, G.M
AU - Furniss, B S
PY - 1967
DA - 1967/01/01
PB - Royal Society of Chemistry (RSC)
SP - 869
SN - 0022-4952
ER -
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@article{1967_Brooke,
author = {G.M Brooke and B S Furniss},
title = {Partially fluorinated heterocyclic compounds. Part III. The preparation of 4,5,6,7-tetrafluorobenzo[b]furan},
journal = {Journal of the Chemical Society C Organic},
year = {1967},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/j39670000869},
pages = {869},
doi = {10.1039/j39670000869}
}