Anodic oxidation. Part VIII. Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide
Publication type: Journal Article
Publication date: 1970-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224952
Organic Chemistry
Abstract
Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide gives tetramethyl ethane-1,1,2,2-tetracarboxylate, tetramethyl propane-1,1,3,3-tetracarboxylate, and hexamethyl propane-1,1,2,2,3,3-hexacarboxylate. Degradation of the solvent to pentamethylphosphoric triamide occurs; mechanisms for the loss of the N-methyl group and for its subsequent incorporation into the second of the above products are discussed.
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9
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Brettle R., Seddon D. Anodic oxidation. Part VIII. Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide // Journal of the Chemical Society C Organic. 1970. Vol. 9. p. 1153.
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Brettle R., Seddon D. Anodic oxidation. Part VIII. Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide // Journal of the Chemical Society C Organic. 1970. Vol. 9. p. 1153.
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TY - JOUR
DO - 10.1039/j39700001153
UR - https://doi.org/10.1039/j39700001153
TI - Anodic oxidation. Part VIII. Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide
T2 - Journal of the Chemical Society C Organic
AU - Brettle, R.
AU - Seddon, D.
PY - 1970
DA - 1970/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1153
IS - 9
SN - 0022-4952
ER -
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@article{1970_Brettle,
author = {R. Brettle and D. Seddon},
title = {Anodic oxidation. Part VIII. Electrolysis of dimethyl sodiomalonate in hexamethylphosphoric triamide},
journal = {Journal of the Chemical Society C Organic},
year = {1970},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/j39700001153},
number = {9},
pages = {1153},
doi = {10.1039/j39700001153}
}