Mechanistic studies in the chemistry of urea. Part 4. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with benzil in acid solution
Тип публикации: Journal Article
Дата публикации: 1980-01-01
SJR: 0.791
CiteScore: —
Impact factor: —
ISSN: 03009580, 13645471, 1472779X
General Environmental Science
General Earth and Planetary Sciences
Краткое описание
In acid solution benzil reacts with urea and with 1-methylurea to give the bicyclic products (2) and (3b) and with 1,3-dimethylurea to give 1,3-dimethyl-5,5-diphenylhydantoin (5). The initial step in the reaction is attack by urea on protonated benzil to give the diol (6). Further reaction of (6) is governed by its tendency to eliminate water.
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Butler A. R., Leitch E. Mechanistic studies in the chemistry of urea. Part 4. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with benzil in acid solution // Journal of the Chemical Society Perkin Transactions 2. 1980. Vol. 1. p. 103.
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Butler A. R., Leitch E. Mechanistic studies in the chemistry of urea. Part 4. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with benzil in acid solution // Journal of the Chemical Society Perkin Transactions 2. 1980. Vol. 1. p. 103.
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TY - JOUR
DO - 10.1039/p29800000103
UR - https://doi.org/10.1039/p29800000103
TI - Mechanistic studies in the chemistry of urea. Part 4. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with benzil in acid solution
T2 - Journal of the Chemical Society Perkin Transactions 2
AU - Butler, Anthony R.
AU - Leitch, Elizabeth
PY - 1980
DA - 1980/01/01
PB - Royal Society of Chemistry (RSC)
SP - 103
IS - 1
SN - 0300-9580
SN - 1364-5471
SN - 1472-779X
ER -
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@article{1980_Butler,
author = {Anthony R. Butler and Elizabeth Leitch},
title = {Mechanistic studies in the chemistry of urea. Part 4. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with benzil in acid solution},
journal = {Journal of the Chemical Society Perkin Transactions 2},
year = {1980},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/p29800000103},
number = {1},
pages = {103},
doi = {10.1039/p29800000103}
}
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