The real free energies of solvation of ions in some non-aqueous and mixed solvents
Тип публикации: Journal Article
Дата публикации: 1967-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00147672
Physical and Theoretical Chemistry
General Physics and Astronomy
General Engineering
Краткое описание
Real free energies of solvation have been measured in several non-aqueous and mixed solvents. The results are discussed in terms of the bulk and surface contributions. Changes in these can be deduced in mixed solvents by comparison with the known surface composition. Hence it is proposed that most of the non-aqueous solutions studied have negative χ-potentials and approximate values are suggested which fit the available facts. The sign of the χ-potential of water is still uncertain although the range of possible values has been narrowed. Methanol, unlike the higher alcohols, appears to be oriented differently at the air and uncharged mercury interfaces.
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Case B., Parsons R. The real free energies of solvation of ions in some non-aqueous and mixed solvents // Transactions of the Faraday Society. 1967. Vol. 63. p. 1224.
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Case B., Parsons R. The real free energies of solvation of ions in some non-aqueous and mixed solvents // Transactions of the Faraday Society. 1967. Vol. 63. p. 1224.
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TY - JOUR
DO - 10.1039/tf9676301224
UR - https://doi.org/10.1039/tf9676301224
TI - The real free energies of solvation of ions in some non-aqueous and mixed solvents
T2 - Transactions of the Faraday Society
AU - Case, Brian
AU - Parsons, Roger
PY - 1967
DA - 1967/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1224
VL - 63
SN - 0014-7672
ER -
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@article{1967_Case,
author = {Brian Case and Roger Parsons},
title = {The real free energies of solvation of ions in some non-aqueous and mixed solvents},
journal = {Transactions of the Faraday Society},
year = {1967},
volume = {63},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/tf9676301224},
pages = {1224},
doi = {10.1039/tf9676301224}
}