Synthesis, volume 2009, issue 18, pages 3157-3161
Total Synthesis of Xestodecalactone C from l-Malic Acid
J. S. Yadav
,
Y. Gopala Rao
,
K. Ravindar
,
B. Venkata Rami Reddy
,
A. Narsaiah
Publication type: Journal Article
Publication date: 2009-08-14
Catalysis
Organic Chemistry
Abstract
An efficient total synthesis of the ten-membered macrolide, xestodecalactone C is described. The synthetic sequence uses Barbier-allylation, LiAlH 4 /LiI-mediated syn-stereoselective 1,3-asymmetric reduction, and intramolecular Friedel―Crafts acylation as key steps.
Found
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