volume 52 issue 17 pages 2469-2482

Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions

Wenjing Xiao
Jiarong Chen
Publication typeJournal Article
Publication date2020-07-06
scimago Q2
wos Q2
SJR0.559
CiteScore4.6
Impact factor2.3
ISSN00397881, 1437210X
Catalysis
Organic Chemistry
Abstract

1,3,5-Trisubstituted 1,3,5-triazinanes (hexahydro-1,3,5-triazines), as stable and readily available surrogates for formaldimines, have found extensive applications for the construction of various nitrogen-containing compounds. The formaldimines, formed in situ from this reagent class, can participate in various aminomethylation and cycloaddition­ reactions. This short review presents recent advances in this field with emphasis on the conceptual ideas behind the developed methodologies and the reaction mechanisms.

1 Introduction

2 Aminomethylations with 1,3,5-Triazinanes

3 Cycloadditions with 1,3,5-Triazinanes

3.1 Use of 1,3,5-Triazinanes as Two-Atom Synthons

3.2 Use of 1,3,5-Triazinanes as Three-Atom Synthons

3.3 Use of 1,3,5-Triazinanes as Four-Atom Synthons

3.4 Use of 1,3,5-Triazinanes as Six-Atom Synthons

4 Conclusions

Found 
Found 

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GOST |
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GOST Copy
Xiao W., Chen J. Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions // Synthesis. 2020. Vol. 52. No. 17. pp. 2469-2482.
GOST all authors (up to 50) Copy
Xiao W., Chen J. Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions // Synthesis. 2020. Vol. 52. No. 17. pp. 2469-2482.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1055/s-0040-1707160
UR - https://doi.org/10.1055/s-0040-1707160
TI - Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions
T2 - Synthesis
AU - Xiao, Wenjing
AU - Chen, Jiarong
PY - 2020
DA - 2020/07/06
PB - Georg Thieme Verlag KG
SP - 2469-2482
IS - 17
VL - 52
SN - 0039-7881
SN - 1437-210X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Xiao,
author = {Wenjing Xiao and Jiarong Chen},
title = {Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions},
journal = {Synthesis},
year = {2020},
volume = {52},
publisher = {Georg Thieme Verlag KG},
month = {jul},
url = {https://doi.org/10.1055/s-0040-1707160},
number = {17},
pages = {2469--2482},
doi = {10.1055/s-0040-1707160}
}
MLA
Cite this
MLA Copy
Xiao, Wenjing, and Jiarong Chen. “Recent Advances of 1,3,5-Triazinanes in Aminomethylation and Cycloaddition Reactions.” Synthesis, vol. 52, no. 17, Jul. 2020, pp. 2469-2482. https://doi.org/10.1055/s-0040-1707160.