A General Synthesis of 3,5-Dihalo-2H-1,4-oxazin-2-ones from Cyanohydrins
Publication type: Journal Article
Publication date: 1990-01-01
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
In a novel approach starting from O-trimethylsilyl protected or unprotected cyanohydrins and oxalyl chloride or bromide, a series of unkown 6-substituted 3,5-dihalo-2H,1,4-oxazin-2-ones were prepared. The method was shown to be efficient for various types of cyanohydrins; however cyclization was not obtained with cyanohydrins containing bulky substituents, electron-rich aryl or heteroaryl groups. A mechanism is proposed.
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31
Total citations:
31
Citations from 2024:
1
(3.23%)
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GOST
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Meerpoel L., Hoornaert G. A General Synthesis of 3,5-Dihalo-2H-1,4-oxazin-2-ones from Cyanohydrins // Synthesis. 1990. Vol. 1990. No. 10. pp. 905-908.
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Meerpoel L., Hoornaert G. A General Synthesis of 3,5-Dihalo-2H-1,4-oxazin-2-ones from Cyanohydrins // Synthesis. 1990. Vol. 1990. No. 10. pp. 905-908.
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RIS
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TY - JOUR
DO - 10.1055/s-1990-27049
UR - https://doi.org/10.1055/s-1990-27049
TI - A General Synthesis of 3,5-Dihalo-2H-1,4-oxazin-2-ones from Cyanohydrins
T2 - Synthesis
AU - Meerpoel, Lieven
AU - Hoornaert, Georges
PY - 1990
DA - 1990/01/01
PB - Georg Thieme Verlag KG
SP - 905-908
IS - 10
VL - 1990
SN - 0039-7881
SN - 1437-210X
ER -
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BibTex (up to 50 authors)
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@article{1990_Meerpoel,
author = {Lieven Meerpoel and Georges Hoornaert},
title = {A General Synthesis of 3,5-Dihalo-2H-1,4-oxazin-2-ones from Cyanohydrins},
journal = {Synthesis},
year = {1990},
volume = {1990},
publisher = {Georg Thieme Verlag KG},
month = {jan},
url = {https://doi.org/10.1055/s-1990-27049},
number = {10},
pages = {905--908},
doi = {10.1055/s-1990-27049}
}
Cite this
MLA
Copy
Meerpoel, Lieven, and Georges Hoornaert. “A General Synthesis of 3,5-Dihalo-2H-1,4-oxazin-2-ones from Cyanohydrins.” Synthesis, vol. 1990, no. 10, Jan. 1990, pp. 905-908. https://doi.org/10.1055/s-1990-27049.