Lipase-Catalyzed Asymmetric Dealkoxylcarbonylation of σ-Symmetrical β-Ketodiesters and Its Application to the Synthesis of (-)-Podocarpic Acid
Publication type: Journal Article
Publication date: 2005-10-27
scimago Q3
wos Q3
SJR: 0.437
CiteScore: 3.3
Impact factor: 1.4
ISSN: 09365214, 14372096
Organic Chemistry
Abstract
Optically active 2,6-dimethylcyclohexanone-2-carboxylate was prepared by PLE-catalyzed dealkoxycarbonylation of σ-symmetrical β-ketodiesters, which possess quartemary carbons at α- and α'-positions. Moreover, (-)-podocarpic acid was prepared in a short sequence from 2,6-dimethylcyclohexanone-2-carboxylate.
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Node M. et al. Lipase-Catalyzed Asymmetric Dealkoxylcarbonylation of σ-Symmetrical β-Ketodiesters and Its Application to the Synthesis of (-)-Podocarpic Acid // Synlett. 2005. Vol. 2005. No. 19. pp. 2919-2922.
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Node M., Katoh T., Awasaguchi K. I., Mori D., Kimura H., Kajimoto T. Lipase-Catalyzed Asymmetric Dealkoxylcarbonylation of σ-Symmetrical β-Ketodiesters and Its Application to the Synthesis of (-)-Podocarpic Acid // Synlett. 2005. Vol. 2005. No. 19. pp. 2919-2922.
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TY - JOUR
DO - 10.1055/s-2005-918962
UR - https://doi.org/10.1055/s-2005-918962
TI - Lipase-Catalyzed Asymmetric Dealkoxylcarbonylation of σ-Symmetrical β-Ketodiesters and Its Application to the Synthesis of (-)-Podocarpic Acid
T2 - Synlett
AU - Node, Manabu
AU - Katoh, Takahiro
AU - Awasaguchi, Ken Ichiro
AU - Mori, Daisuke
AU - Kimura, Hiroyuki
AU - Kajimoto, Tetsuya
PY - 2005
DA - 2005/10/27
PB - Georg Thieme Verlag KG
SP - 2919-2922
IS - 19
VL - 2005
SN - 0936-5214
SN - 1437-2096
ER -
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@article{2005_Node,
author = {Manabu Node and Takahiro Katoh and Ken Ichiro Awasaguchi and Daisuke Mori and Hiroyuki Kimura and Tetsuya Kajimoto},
title = {Lipase-Catalyzed Asymmetric Dealkoxylcarbonylation of σ-Symmetrical β-Ketodiesters and Its Application to the Synthesis of (-)-Podocarpic Acid},
journal = {Synlett},
year = {2005},
volume = {2005},
publisher = {Georg Thieme Verlag KG},
month = {oct},
url = {https://doi.org/10.1055/s-2005-918962},
number = {19},
pages = {2919--2922},
doi = {10.1055/s-2005-918962}
}
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MLA
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Node, Manabu, et al. “Lipase-Catalyzed Asymmetric Dealkoxylcarbonylation of σ-Symmetrical β-Ketodiesters and Its Application to the Synthesis of (-)-Podocarpic Acid.” Synlett, vol. 2005, no. 19, Oct. 2005, pp. 2919-2922. https://doi.org/10.1055/s-2005-918962.