Synthesis of Substituted β-Styrylmalonates by Sequential Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates and (2-Arylethylidene)malonates
Publication type: Journal Article
Publication date: 2021-01-08
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
A method has been developed for the synthesis of substituted β-styrylmalonates by conversion of 2-arylcyclopropane-1,1-dicarboxylates (ACDCs) in the presence of gallium trichloride into the corresponding 1,2-zwitterionic intermediates or (2-arylethylidene)malonates, followed by treatment with pyridine at room temperature leading to an isomerization of the emerging double bond. This method allows one to expand these reactions to include ACDCs with acceptor substituents at the aromatic ring.
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Total citations:
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Citations from 2025:
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(14.29%)
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Novikov R. A. et al. Synthesis of Substituted β-Styrylmalonates by Sequential Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates and (2-Arylethylidene)malonates // Synthesis. 2021. Vol. 53. No. 13. pp. 2253-2259.
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Novikov R. A., Tomilov Y. V., Borisov D. D., Chermashentsev G. R. Synthesis of Substituted β-Styrylmalonates by Sequential Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates and (2-Arylethylidene)malonates // Synthesis. 2021. Vol. 53. No. 13. pp. 2253-2259.
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TY - JOUR
DO - 10.1055/a-1348-4311
UR - https://doi.org/10.1055/a-1348-4311
TI - Synthesis of Substituted β-Styrylmalonates by Sequential Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates and (2-Arylethylidene)malonates
T2 - Synthesis
AU - Novikov, Roman A
AU - Tomilov, Yury V
AU - Borisov, Denis D
AU - Chermashentsev, Grigorii R
PY - 2021
DA - 2021/01/08
PB - Georg Thieme Verlag KG
SP - 2253-2259
IS - 13
VL - 53
SN - 0039-7881
SN - 1437-210X
ER -
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BibTex (up to 50 authors)
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@article{2021_Novikov,
author = {Roman A Novikov and Yury V Tomilov and Denis D Borisov and Grigorii R Chermashentsev},
title = {Synthesis of Substituted β-Styrylmalonates by Sequential Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates and (2-Arylethylidene)malonates},
journal = {Synthesis},
year = {2021},
volume = {53},
publisher = {Georg Thieme Verlag KG},
month = {jan},
url = {https://doi.org/10.1055/a-1348-4311},
number = {13},
pages = {2253--2259},
doi = {10.1055/a-1348-4311}
}
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MLA
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Novikov, Roman A., et al. “Synthesis of Substituted β-Styrylmalonates by Sequential Isomerization of 2-Arylcyclopropane-1,1-dicarboxylates and (2-Arylethylidene)malonates.” Synthesis, vol. 53, no. 13, Jan. 2021, pp. 2253-2259. https://doi.org/10.1055/a-1348-4311.
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