Synthetic Approach to Alkoxy-β-(trifluoromethyl)styrenesand Their Application in the Synthesis of New TrifluoromethylatedHeterocycles
Publication type: Journal Article
Publication date: 2009-05-12
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
A new convenient stereoselective pathway to alkoxy-β-(trifluoromethyl)styrenes is described. Reactions of β-chloro- and β-bromo-β-(trifluoromethyl)styrenes with sodium methoxide and potassium tert-butoxide led to methoxy- and tert-butoxy-β-(trifluoromethyl)styrenes in good to excellent yields. Bromination of tertbutoxy-β-(trifluoromethyl)styrenes proceeded with formation of aryl(bromo)methyl trifluoromethyl ketones. The latter compounds were found to be useful starting materials for the synthesis of different heterocyclic compounds bearing a trifluoromethyl group. In this way trifluoromethylated derivatives of imidazopyridine, imidazopyrimidine, imidazobenzimidazole, imidazothiazole, thiazole, and aminothiazole were obtained in moderate to high yield.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Chemistry of Heterocyclic Compounds
2 publications, 18.18%
|
|
|
Pharmaceutical Chemistry Journal
1 publication, 9.09%
|
|
|
Tetrahedron Letters
1 publication, 9.09%
|
|
|
ACS Omega
1 publication, 9.09%
|
|
|
Organic Letters
1 publication, 9.09%
|
|
|
Journal of Organic Chemistry
1 publication, 9.09%
|
|
|
Russian Chemical Reviews
1 publication, 9.09%
|
|
|
Russian Journal of Organic Chemistry
1 publication, 9.09%
|
|
|
Журнал органической химии
1 publication, 9.09%
|
|
|
Journal of the Turkish Chemical Society, Section A: Chemistry
1 publication, 9.09%
|
|
|
1
2
|
Publishers
|
1
2
3
|
|
|
Springer Nature
3 publications, 27.27%
|
|
|
American Chemical Society (ACS)
3 publications, 27.27%
|
|
|
Elsevier
1 publication, 9.09%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 9.09%
|
|
|
Pleiades Publishing
1 publication, 9.09%
|
|
|
The Russian Academy of Sciences
1 publication, 9.09%
|
|
|
Turkish Chemical Society
1 publication, 9.09%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
11
Total citations:
11
Citations from 2024:
3
(27.27%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Muzalevskiy V. M. et al. Synthetic Approach to Alkoxy-β-(trifluoromethyl)styrenesand Their Application in the Synthesis of New TrifluoromethylatedHeterocycles // Synthesis. 2009. Vol. 2009. No. 13. pp. 2249-2259.
GOST all authors (up to 50)
Copy
Muzalevskiy V. M., Nenajdenko V. G., Muzalevskiy V., Shastin A., Haufe G. Synthetic Approach to Alkoxy-β-(trifluoromethyl)styrenesand Their Application in the Synthesis of New TrifluoromethylatedHeterocycles // Synthesis. 2009. Vol. 2009. No. 13. pp. 2249-2259.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1055/s-0029-1216697
UR - https://doi.org/10.1055/s-0029-1216697
TI - Synthetic Approach to Alkoxy-β-(trifluoromethyl)styrenesand Their Application in the Synthesis of New TrifluoromethylatedHeterocycles
T2 - Synthesis
AU - Muzalevskiy, Vasily M.
AU - Nenajdenko, Valentine G.
AU - Muzalevskiy, Vasiliy
AU - Shastin, Aleksey
AU - Haufe, Gunter
PY - 2009
DA - 2009/05/12
PB - Georg Thieme Verlag KG
SP - 2249-2259
IS - 13
VL - 2009
SN - 0039-7881
SN - 1437-210X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Muzalevskiy,
author = {Vasily M. Muzalevskiy and Valentine G. Nenajdenko and Vasiliy Muzalevskiy and Aleksey Shastin and Gunter Haufe},
title = {Synthetic Approach to Alkoxy-β-(trifluoromethyl)styrenesand Their Application in the Synthesis of New TrifluoromethylatedHeterocycles},
journal = {Synthesis},
year = {2009},
volume = {2009},
publisher = {Georg Thieme Verlag KG},
month = {may},
url = {https://doi.org/10.1055/s-0029-1216697},
number = {13},
pages = {2249--2259},
doi = {10.1055/s-0029-1216697}
}
Cite this
MLA
Copy
Muzalevskiy, Vasily M., et al. “Synthetic Approach to Alkoxy-β-(trifluoromethyl)styrenesand Their Application in the Synthesis of New TrifluoromethylatedHeterocycles.” Synthesis, vol. 2009, no. 13, May. 2009, pp. 2249-2259. https://doi.org/10.1055/s-0029-1216697.