A Metal-Free, Three-Component Manifold for the C2-Functionalization of 1-Substituted Imidazoles Operating ‘On Water’
Publication type: Journal Article
Publication date: 2010-09-03
scimago Q3
wos Q3
SJR: 0.437
CiteScore: 3.3
Impact factor: 1.4
ISSN: 09365214, 14372096
Organic Chemistry
Abstract
A metal-free, three-component process for the C2-func- tionalization of N-alkylated imidazoles is reported The multicom- ponent manifold operates under 'on water' conditions through the formation of a water-stable (permanent) nucleophilic imidazole car- bene (imidazolium ylide). Whereas the incorporated vinyl ether functionality is a convenient handle for further chemical manipula- tion of the functionalized heterocycle (complexity generation), the use of water as the reaction media gives it a bonus of added benefits in terms of safety, bench-friendly processing and environmental care.
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De Armas P., García-Tellado F. A Metal-Free, Three-Component Manifold for the C2-Functionalization of 1-Substituted Imidazoles Operating ‘On Water’ // Synlett. 2010. Vol. 2010. No. 16. pp. 2421-2424.
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De Armas P., García-Tellado F. A Metal-Free, Three-Component Manifold for the C2-Functionalization of 1-Substituted Imidazoles Operating ‘On Water’ // Synlett. 2010. Vol. 2010. No. 16. pp. 2421-2424.
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TY - JOUR
DO - 10.1055/s-0030-1258561
UR - https://doi.org/10.1055/s-0030-1258561
TI - A Metal-Free, Three-Component Manifold for the C2-Functionalization of 1-Substituted Imidazoles Operating ‘On Water’
T2 - Synlett
AU - De Armas, Pedro
AU - García-Tellado, Fernando
PY - 2010
DA - 2010/09/03
PB - Georg Thieme Verlag KG
SP - 2421-2424
IS - 16
VL - 2010
SN - 0936-5214
SN - 1437-2096
ER -
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BibTex (up to 50 authors)
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@article{2010_De Armas,
author = {Pedro De Armas and Fernando García-Tellado},
title = {A Metal-Free, Three-Component Manifold for the C2-Functionalization of 1-Substituted Imidazoles Operating ‘On Water’},
journal = {Synlett},
year = {2010},
volume = {2010},
publisher = {Georg Thieme Verlag KG},
month = {sep},
url = {https://doi.org/10.1055/s-0030-1258561},
number = {16},
pages = {2421--2424},
doi = {10.1055/s-0030-1258561}
}
Cite this
MLA
Copy
De Armas, Pedro, and Fernando García-Tellado. “A Metal-Free, Three-Component Manifold for the C2-Functionalization of 1-Substituted Imidazoles Operating ‘On Water’.” Synlett, vol. 2010, no. 16, Sep. 2010, pp. 2421-2424. https://doi.org/10.1055/s-0030-1258561.