A Convenient Synthesis of α-Substituted β,γ-Unsaturated Ketones and Esters via the Direct Addition of Substituted Allylic Zinc Reagents Prepared by Direct Insertion
Тип публикации: Journal Article
Дата публикации: 2013-04-30
scimago Q2
wos Q2
white level БС2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Краткое описание
A practical and convenient procedure for the synthesis of α-substituted β,γ-unsaturated ketones and esters has been developed. Substituted allylic zinc reagents, prepared via direct metal insertion in substituted allylic halides, react readily with a broad range of acid chlorides and chloroformates furnishing the corresponding α-substituted β,γ-unsaturated ketones and esters in high yield and perfect regioselectivity.
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Knochel P., Knochel P. A Convenient Synthesis of α-Substituted β,γ-Unsaturated Ketones and Esters via the Direct Addition of Substituted Allylic Zinc Reagents Prepared by Direct Insertion // Synthesis. 2013. Vol. 45. No. 13. pp. 1870-1876.
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Knochel P., Knochel P. A Convenient Synthesis of α-Substituted β,γ-Unsaturated Ketones and Esters via the Direct Addition of Substituted Allylic Zinc Reagents Prepared by Direct Insertion // Synthesis. 2013. Vol. 45. No. 13. pp. 1870-1876.
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TY - JOUR
DO - 10.1055/s-0033-1338415
UR - https://doi.org/10.1055/s-0033-1338415
TI - A Convenient Synthesis of α-Substituted β,γ-Unsaturated Ketones and Esters via the Direct Addition of Substituted Allylic Zinc Reagents Prepared by Direct Insertion
T2 - Synthesis
AU - Knochel, Paul
AU - Knochel, Paul
PY - 2013
DA - 2013/04/30
PB - Georg Thieme Verlag KG
SP - 1870-1876
IS - 13
VL - 45
SN - 0039-7881
SN - 1437-210X
ER -
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BibTex (до 50 авторов)
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@article{2013_Knochel,
author = {Paul Knochel and Paul Knochel},
title = {A Convenient Synthesis of α-Substituted β,γ-Unsaturated Ketones and Esters via the Direct Addition of Substituted Allylic Zinc Reagents Prepared by Direct Insertion},
journal = {Synthesis},
year = {2013},
volume = {45},
publisher = {Georg Thieme Verlag KG},
month = {apr},
url = {https://doi.org/10.1055/s-0033-1338415},
number = {13},
pages = {1870--1876},
doi = {10.1055/s-0033-1338415}
}
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MLA
Скопировать
Knochel, Paul, and Paul Knochel. “A Convenient Synthesis of α-Substituted β,γ-Unsaturated Ketones and Esters via the Direct Addition of Substituted Allylic Zinc Reagents Prepared by Direct Insertion.” Synthesis, vol. 45, no. 13, Apr. 2013, pp. 1870-1876. https://doi.org/10.1055/s-0033-1338415.
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