A Short and Efficient Approach to Pyrrolo[2,1-a]isoquinoline and Pyrrolo[2,1-a]benzazepine Derivatives
Publication type: Journal Article
Publication date: 2016-03-09
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
A Bronsted acid promoted intramolecular Friedel–Crafts cyclization of β-benzoyl- and β-acetylpyrrol-2(5H)-one derivatives tethered via nitrogen to an electron-rich arene nucleus is developed. Using this efficient methodology, various pyrrolo[2,1-a]isoquinoline and pyrrolo[2,1-a]benzazepine derivatives are prepared in a two-step sequence starting from readily available ethyl (Z)-3-bromomethyl-4-oxo-4-phenylbut-2-enoate or ethyl (Z)-3-bromomethyl-4-oxopent-2-enoate.
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GOST
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Amri H. et al. A Short and Efficient Approach to Pyrrolo[2,1-a]isoquinoline and Pyrrolo[2,1-a]benzazepine Derivatives // Synthesis. 2016. Vol. 48. No. 10. pp. 1502-1517.
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Amri H., Mathé-Allainmat M., Lebreton J., Jebali K., Lebreton J. A Short and Efficient Approach to Pyrrolo[2,1-a]isoquinoline and Pyrrolo[2,1-a]benzazepine Derivatives // Synthesis. 2016. Vol. 48. No. 10. pp. 1502-1517.
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RIS
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TY - JOUR
DO - 10.1055/s-0035-1561398
UR - https://doi.org/10.1055/s-0035-1561398
TI - A Short and Efficient Approach to Pyrrolo[2,1-a]isoquinoline and Pyrrolo[2,1-a]benzazepine Derivatives
T2 - Synthesis
AU - Amri, Hassen
AU - Mathé-Allainmat, Monique
AU - Lebreton, Jacques
AU - Jebali, Khaoula
AU - Lebreton, Jacques
PY - 2016
DA - 2016/03/09
PB - Georg Thieme Verlag KG
SP - 1502-1517
IS - 10
VL - 48
SN - 0039-7881
SN - 1437-210X
ER -
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BibTex (up to 50 authors)
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@article{2016_Amri,
author = {Hassen Amri and Monique Mathé-Allainmat and Jacques Lebreton and Khaoula Jebali and Jacques Lebreton},
title = {A Short and Efficient Approach to Pyrrolo[2,1-a]isoquinoline and Pyrrolo[2,1-a]benzazepine Derivatives},
journal = {Synthesis},
year = {2016},
volume = {48},
publisher = {Georg Thieme Verlag KG},
month = {mar},
url = {https://doi.org/10.1055/s-0035-1561398},
number = {10},
pages = {1502--1517},
doi = {10.1055/s-0035-1561398}
}
Cite this
MLA
Copy
Amri, Hassen, et al. “A Short and Efficient Approach to Pyrrolo[2,1-a]isoquinoline and Pyrrolo[2,1-a]benzazepine Derivatives.” Synthesis, vol. 48, no. 10, Mar. 2016, pp. 1502-1517. https://doi.org/10.1055/s-0035-1561398.