Lewis Acid Catalyzed Friedel-Crafts Alkylation of Indoles and Other Electron-Rich Aromatic Compounds with Ethyl 2-(Diethoxyphosphoryl)acrylate and Tetraethyl Ethene-1,1-diylbis(phosphonate)
Publication type: Journal Article
Publication date: 2016-12-01
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
Friedel–Crafts alkylation of indoles and other electron-rich aromatic compounds with ethyl 2-(diethoxyphosphoryl)acrylate and tetraethyl ethene-1,1-diylbis(phosphonate) was carried out in the presence of 5 mol% Cu(ClO4)2·6H2O/2,2′-Bipy complex as a catalyst in acetonitrile at room temperature to afford a broad series of heteroaryl- and aryl-substituted 2-(diethoxyphosphoryl)propionates and ethyl-1,1-diylbis(phosphonates) in 58–96% yield.
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Beletskaya I., Beletskaya I. P. Lewis Acid Catalyzed Friedel-Crafts Alkylation of Indoles and Other Electron-Rich Aromatic Compounds with Ethyl 2-(Diethoxyphosphoryl)acrylate and Tetraethyl Ethene-1,1-diylbis(phosphonate) // Synthesis. 2016. Vol. 49. No. 7. pp. 1689-1701.
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Beletskaya I., Beletskaya I. P. Lewis Acid Catalyzed Friedel-Crafts Alkylation of Indoles and Other Electron-Rich Aromatic Compounds with Ethyl 2-(Diethoxyphosphoryl)acrylate and Tetraethyl Ethene-1,1-diylbis(phosphonate) // Synthesis. 2016. Vol. 49. No. 7. pp. 1689-1701.
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TY - JOUR
DO - 10.1055/s-0036-1588660
UR - https://doi.org/10.1055/s-0036-1588660
TI - Lewis Acid Catalyzed Friedel-Crafts Alkylation of Indoles and Other Electron-Rich Aromatic Compounds with Ethyl 2-(Diethoxyphosphoryl)acrylate and Tetraethyl Ethene-1,1-diylbis(phosphonate)
T2 - Synthesis
AU - Beletskaya, Irina
AU - Beletskaya, Irina P.
PY - 2016
DA - 2016/12/01
PB - Georg Thieme Verlag KG
SP - 1689-1701
IS - 7
VL - 49
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2016_Beletskaya,
author = {Irina Beletskaya and Irina P. Beletskaya},
title = {Lewis Acid Catalyzed Friedel-Crafts Alkylation of Indoles and Other Electron-Rich Aromatic Compounds with Ethyl 2-(Diethoxyphosphoryl)acrylate and Tetraethyl Ethene-1,1-diylbis(phosphonate)},
journal = {Synthesis},
year = {2016},
volume = {49},
publisher = {Georg Thieme Verlag KG},
month = {dec},
url = {https://doi.org/10.1055/s-0036-1588660},
number = {7},
pages = {1689--1701},
doi = {10.1055/s-0036-1588660}
}
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Beletskaya, Irina, and Irina P. Beletskaya. “Lewis Acid Catalyzed Friedel-Crafts Alkylation of Indoles and Other Electron-Rich Aromatic Compounds with Ethyl 2-(Diethoxyphosphoryl)acrylate and Tetraethyl Ethene-1,1-diylbis(phosphonate).” Synthesis, vol. 49, no. 7, Dec. 2016, pp. 1689-1701. https://doi.org/10.1055/s-0036-1588660.
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