volume 28 issue 19 pages 4523-4534

Zirconium-Catalyzed Alkyne Carbo- and Cycloalumination Reactions in Stereoselective Preparation of 1-Alkenyl Selenides

Rita N. Kadikova 1
Ilfir R Ramazanov 1
Alexey Vyatkin 1
Usein M Dzhemilev 1
Publication typeJournal Article
Publication date2017-07-20
scimago Q2
wos Q2
SJR0.559
CiteScore4.6
Impact factor2.3
ISSN00397881, 1437210X
Catalysis
Organic Chemistry
Abstract

The Cp2ZrCl2-catalyzed methylalumination and сycloalumination of 1-alkynyl selenides followed by deuterolysis or hydrolysis affords corresponding (Z)-1-alkenyl selenides in high yields. Alternatively, (E)-1-alkenyl selenides were prepared by the reaction of 1-alkenylaluminums with organic diselenides in a one-pot procedure starting from the corresponding 1-alkynes, which provides a versatile tool for the preparation of stereo-defined unsaturated organic derivatives of selenium.

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GOST |
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GOST Copy
Kadikova R. N. et al. Zirconium-Catalyzed Alkyne Carbo- and Cycloalumination Reactions in Stereoselective Preparation of 1-Alkenyl Selenides // Synthesis. 2017. Vol. 28. No. 19. pp. 4523-4534.
GOST all authors (up to 50) Copy
Kadikova R. N., Ramazanov I. R., Vyatkin A., Dzhemilev U. M. Zirconium-Catalyzed Alkyne Carbo- and Cycloalumination Reactions in Stereoselective Preparation of 1-Alkenyl Selenides // Synthesis. 2017. Vol. 28. No. 19. pp. 4523-4534.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1055/s-0036-1589062
UR - https://doi.org/10.1055/s-0036-1589062
TI - Zirconium-Catalyzed Alkyne Carbo- and Cycloalumination Reactions in Stereoselective Preparation of 1-Alkenyl Selenides
T2 - Synthesis
AU - Kadikova, Rita N.
AU - Ramazanov, Ilfir R
AU - Vyatkin, Alexey
AU - Dzhemilev, Usein M
PY - 2017
DA - 2017/07/20
PB - Georg Thieme Verlag KG
SP - 4523-4534
IS - 19
VL - 28
SN - 0039-7881
SN - 1437-210X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Kadikova,
author = {Rita N. Kadikova and Ilfir R Ramazanov and Alexey Vyatkin and Usein M Dzhemilev},
title = {Zirconium-Catalyzed Alkyne Carbo- and Cycloalumination Reactions in Stereoselective Preparation of 1-Alkenyl Selenides},
journal = {Synthesis},
year = {2017},
volume = {28},
publisher = {Georg Thieme Verlag KG},
month = {jul},
url = {https://doi.org/10.1055/s-0036-1589062},
number = {19},
pages = {4523--4534},
doi = {10.1055/s-0036-1589062}
}
MLA
Cite this
MLA Copy
Kadikova, Rita N., et al. “Zirconium-Catalyzed Alkyne Carbo- and Cycloalumination Reactions in Stereoselective Preparation of 1-Alkenyl Selenides.” Synthesis, vol. 28, no. 19, Jul. 2017, pp. 4523-4534. https://doi.org/10.1055/s-0036-1589062.