Synthesis

, том 50 , издание 21 , страницы 4283-4289

Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives

Pavel Troshin ^{1, 2}

Liangbing Gan ^{3, 4}

Ning Lou ³

Olga Kraevaya ¹

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Institute for Problems of Chemical Physics of Russian Academy of Sciences |

Skolkovo Institute of Science and Technology |

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University

Пекинский университет

Пекинская национальная лаборатория молекулярных наук

⁴

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry |

Тип публикации: Journal Article

Дата публикации: 2018-07-25

Georg Thieme Verlag KG

Synthesis

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SJR: 0.559

CiteScore: 4.6

Impact factor: 2.3

ISSN: 00397881, 1437210X

DOI: 10.1055/s-0037-1610220

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Catalysis

Organic Chemistry

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Unlike the facile addition of aliphatic amines to fullerenes, heteroaromatic compounds with NH group do not react directly with pristine fullerenes. The present work reports the preparation of several cyclopentadienyl type [60]fullerene derivatives with pyrazole and pyrrole addends through replacement reactions of C60Cl6 in the presence of tetrabutylammonium bromide. The method has also been applied for the synthesis of aniline and methoxyamine [60]fullerene cyclopentadienyl type adducts. Radical species were involved in the reaction mechanism.

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Troshin P. et al. Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives // Synthesis. 2018. Vol. 50. No. 21. pp. 4283-4289.

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Troshin P., Gan L., Lou N., Kraevaya O. Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives // Synthesis. 2018. Vol. 50. No. 21. pp. 4283-4289.

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TY - JOUR

DO - 10.1055/s-0037-1610220

UR - https://doi.org/10.1055/s-0037-1610220

TI - Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives

T2 - Synthesis

AU - Troshin, Pavel

AU - Gan, Liangbing

AU - Lou, Ning

AU - Kraevaya, Olga

PY - 2018

DA - 2018/07/25

PB - Georg Thieme Verlag KG

SP - 4283-4289

IS - 21

VL - 50

SN - 0039-7881

SN - 1437-210X

ER -

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@article{2018_Troshin,

author = {Pavel Troshin and Liangbing Gan and Ning Lou and Olga Kraevaya},

title = {Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives},

journal = {Synthesis},

year = {2018},

volume = {50},

publisher = {Georg Thieme Verlag KG},

month = {jul},

url = {https://doi.org/10.1055/s-0037-1610220},

number = {21},

pages = {4283--4289},

doi = {10.1055/s-0037-1610220}

}

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Troshin, Pavel, et al. “Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C60 Derivatives.” Synthesis, vol. 50, no. 21, Jul. 2018, pp. 4283-4289. https://doi.org/10.1055/s-0037-1610220.