volume 51 issue 06 pages 1445-1454

Metal- and Solvent-free Synthesis of Functionalized Dihydrooxa­zolo[3,2-a]indoles by One-Pot Tandem Assembly of 3H-Indoles and Propargylic Alcohols

Publication typeJournal Article
Publication date2018-11-28
scimago Q2
wos Q2
SJR0.559
CiteScore4.6
Impact factor2.3
ISSN00397881, 1437210X
Catalysis
Organic Chemistry
Abstract

The reaction of 3H-indoles with tertiary propargylic alcohols to give functionalized dihydrooxazolo[3,2-a]indoles in good to excellent yields has been developed. This metal- and solvent-free, one-pot tandem assembly proceeds under mild conditions (22–60 °C) and is regio- and stereoselective: either the Z- or E-isomers (relative to the double bond) are alternatively formed depending on other functionalized substituents on the propargylic alcohols.

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Oparina L. A., Trofimov B. A. Metal- and Solvent-free Synthesis of Functionalized Dihydrooxa­zolo[3,2-a]indoles by One-Pot Tandem Assembly of 3H-Indoles and Propargylic Alcohols // Synthesis. 2018. Vol. 51. No. 06. pp. 1445-1454.
GOST all authors (up to 50) Copy
Oparina L. A., Trofimov B. A. Metal- and Solvent-free Synthesis of Functionalized Dihydrooxa­zolo[3,2-a]indoles by One-Pot Tandem Assembly of 3H-Indoles and Propargylic Alcohols // Synthesis. 2018. Vol. 51. No. 06. pp. 1445-1454.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1055/s-0037-1610319
UR - https://doi.org/10.1055/s-0037-1610319
TI - Metal- and Solvent-free Synthesis of Functionalized Dihydrooxa­zolo[3,2-a]indoles by One-Pot Tandem Assembly of 3H-Indoles and Propargylic Alcohols
T2 - Synthesis
AU - Oparina, Ludmila A.
AU - Trofimov, B. A.
PY - 2018
DA - 2018/11/28
PB - Georg Thieme Verlag KG
SP - 1445-1454
IS - 06
VL - 51
SN - 0039-7881
SN - 1437-210X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Oparina,
author = {Ludmila A. Oparina and B. A. Trofimov},
title = {Metal- and Solvent-free Synthesis of Functionalized Dihydrooxa­zolo[3,2-a]indoles by One-Pot Tandem Assembly of 3H-Indoles and Propargylic Alcohols},
journal = {Synthesis},
year = {2018},
volume = {51},
publisher = {Georg Thieme Verlag KG},
month = {nov},
url = {https://doi.org/10.1055/s-0037-1610319},
number = {06},
pages = {1445--1454},
doi = {10.1055/s-0037-1610319}
}
MLA
Cite this
MLA Copy
Oparina, Ludmila A., and B. A. Trofimov. “Metal- and Solvent-free Synthesis of Functionalized Dihydrooxa­zolo[3,2-a]indoles by One-Pot Tandem Assembly of 3H-Indoles and Propargylic Alcohols.” Synthesis, vol. 51, no. 06, Nov. 2018, pp. 1445-1454. https://doi.org/10.1055/s-0037-1610319.
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