An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode
Тип публикации: Journal Article
Дата публикации: 2019-01-07
SCImago Q2
WOS Q3
БС2
SJR: 0.443
CiteScore: 4.3
Impact factor: 2.2
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Краткое описание
Reaction conditions have been identified to conduct a one-pot asymmetric organocatalytic aldol reaction with a hydrophobic substrate in aqueous medium via a process running in flow mode. By employing a mixture of water and 2-propanol, a hydrophobic aldehyde and 3.6 mol% of an organocatalyst, this microreactor process affords the desired aldol adduct with a conversion of 74% and an enantioselectivity of 89% after a reaction time of 60 minutes.
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ГОСТ
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Schober L. et al. An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode // Synthesis. 2019. Vol. 51. No. 05. pp. 1178-1184.
ГОСТ со всеми авторами (до 50)
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Schober L., Ratnam S., Yamashita Y., Adebar N., Pieper M., Berkessel A., Hessel V., Gröger H. An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode // Synthesis. 2019. Vol. 51. No. 05. pp. 1178-1184.
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RIS
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TY - JOUR
DO - 10.1055/s-0037-1610404
UR - https://doi.org/10.1055/s-0037-1610404
TI - An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode
T2 - Synthesis
AU - Schober, Lukas
AU - Ratnam, Shahilan
AU - Yamashita, Yasunobu
AU - Adebar, Niklas
AU - Pieper, Matthias
AU - Berkessel, Albrecht
AU - Hessel, Volker
AU - Gröger, Harald
PY - 2019
DA - 2019/01/07
PB - Georg Thieme Verlag KG
SP - 1178-1184
IS - 05
VL - 51
SN - 0039-7881
SN - 1437-210X
ER -
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BibTex (до 50 авторов)
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@article{2019_Schober,
author = {Lukas Schober and Shahilan Ratnam and Yasunobu Yamashita and Niklas Adebar and Matthias Pieper and Albrecht Berkessel and Volker Hessel and Harald Gröger},
title = {An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode},
journal = {Synthesis},
year = {2019},
volume = {51},
publisher = {Georg Thieme Verlag KG},
month = {jan},
url = {https://doi.org/10.1055/s-0037-1610404},
number = {05},
pages = {1178--1184},
doi = {10.1055/s-0037-1610404}
}
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MLA
Скопировать
Schober, Lukas, et al. “An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode.” Synthesis, vol. 51, no. 05, Jan. 2019, pp. 1178-1184. https://doi.org/10.1055/s-0037-1610404.
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