Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones
Тип публикации: Journal Article
Дата публикации: 2019-03-04
scimago Q3
wos Q3
БС2
SJR: 0.437
CiteScore: 3.3
Impact factor: 1.4
ISSN: 09365214, 14372096
Organic Chemistry
Краткое описание
Tosyloxy- and mesyloxyflavones derived from abundant and biologically important hydroxyflavones were used to synthesize a series of functionalized flavones through versatile palladium-catalyzed cross-coupling reactions. A Pd(OAc)2/2-[2-(dicyclohexylphosphino)phenyl]-1-methyl-1H-indole system effectively catalyzed the reactions of a broad range of tosyloxy- and mesyloxyflavones as electrophilic coupling partners with various nucleophiles to give the corresponding products in good to excellent yields. Catalyst loadings of as little as 0.1 mol% Pd were successfully used. Importantly, we demonstrated that this protocol provided a significantly improved efficiency in the synthesis of a potential chromen-4-one-based analogue of a potent inhibitor of DNA-dependent protein kinase.
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So C. M. et al. Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones // Synlett. 2019. Vol. 30. No. 06. pp. 731-737.
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So C. M., Yuen O., Pang W., Chen X., Chen Z., Kwong F. Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones // Synlett. 2019. Vol. 30. No. 06. pp. 731-737.
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TY - JOUR
DO - 10.1055/s-0037-1611742
UR - https://doi.org/10.1055/s-0037-1611742
TI - Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones
T2 - Synlett
AU - So, Chau Ming
AU - Yuen, On
AU - Pang, Wai
AU - Chen, Xiangmeng
AU - Chen, Zicong
AU - Kwong, Fuk
PY - 2019
DA - 2019/03/04
PB - Georg Thieme Verlag KG
SP - 731-737
IS - 06
VL - 30
SN - 0936-5214
SN - 1437-2096
ER -
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@article{2019_So,
author = {Chau Ming So and On Yuen and Wai Pang and Xiangmeng Chen and Zicong Chen and Fuk Kwong},
title = {Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones},
journal = {Synlett},
year = {2019},
volume = {30},
publisher = {Georg Thieme Verlag KG},
month = {mar},
url = {https://doi.org/10.1055/s-0037-1611742},
number = {06},
pages = {731--737},
doi = {10.1055/s-0037-1611742}
}
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So, Chau Ming, et al. “Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones.” Synlett, vol. 30, no. 06, Mar. 2019, pp. 731-737. https://doi.org/10.1055/s-0037-1611742.