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Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates
Publication type: Journal Article
Publication date: 2019-11-27
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
A simple synthetic procedure for the Pd-catalyzed hydroarylation of diazoacetic ester has been previously developed in our laboratory. Now we have applied this methodology for hydroarylation of α-diazocarboxylates/α-diazophosphonates. Diazo compounds reacted with aryl iodides and formic acid to afford diarylated esters or phosphonates in yields up to 71%.
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Titanyuk I. D. Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates // Synthesis. 2019. Vol. 52. No. 5. pp. 775-780.
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Titanyuk I. D. Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates // Synthesis. 2019. Vol. 52. No. 5. pp. 775-780.
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RIS
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TY - JOUR
DO - 10.1055/s-0039-1690758
UR - https://doi.org/10.1055/s-0039-1690758
TI - Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates
T2 - Synthesis
AU - Titanyuk, Igor D
PY - 2019
DA - 2019/11/27
PB - Georg Thieme Verlag KG
SP - 775-780
IS - 5
VL - 52
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2019_Titanyuk,
author = {Igor D Titanyuk},
title = {Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates},
journal = {Synthesis},
year = {2019},
volume = {52},
publisher = {Georg Thieme Verlag KG},
month = {nov},
url = {https://doi.org/10.1055/s-0039-1690758},
number = {5},
pages = {775--780},
doi = {10.1055/s-0039-1690758}
}
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MLA
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Titanyuk, Igor D.. “Palladium-Catalyzed Hydroarylation of Diazocarboxylates and Diazophosphonates.” Synthesis, vol. 52, no. 5, Nov. 2019, pp. 775-780. https://doi.org/10.1055/s-0039-1690758.
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