Synlett, volume 32, issue 03, pages 258-266
Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts
N Gabriel Lemcoff
1, 2
,
Noy B Nechmad
1
Publication type: Journal Article
Publication date: 2020-08-07
Organic Chemistry
Abstract
This Account summarizes the historical development of latent sulfur-chelated ruthenium precatalysts from the Lemcoff group’s perspective. The most unique feature of this family of complexes is that they appear in the more stable cis-dichloro configuration, which is latent towards olefin metathesis reactions. Activation of the precatalyst, brought about by isomerization from the cis-dihalo to the trans-dihalo forms, can be achieved either by thermal or light stimuli. Modifications of the ligand sphere bestows unique properties upon the catalysts, which have been used in diverse applications, from 3D printing of metathesis polymers to orthogonally divergent synthetic pathways.
1 Introduction
2 Effect of Sulfur Substituents
3 Effect of Benzylidene Ligands
4 Effect of the NHC Ligands
5 Effect of the Anionic Ligands
6 Conclusions
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- We do not take into account publications without a DOI.
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Lemcoff N. G., Nechmad N. B. Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts // Synlett. 2020. Vol. 32. No. 03. pp. 258-266.
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Lemcoff N. G., Nechmad N. B. Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts // Synlett. 2020. Vol. 32. No. 03. pp. 258-266.
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TY - JOUR
DO - 10.1055/s-0040-1707231
UR - https://doi.org/10.1055/s-0040-1707231
TI - Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts
T2 - Synlett
AU - Lemcoff, N Gabriel
AU - Nechmad, Noy B
PY - 2020
DA - 2020/08/07 00:00:00
PB - Thieme
SP - 258-266
IS - 03
VL - 32
SN - 0936-5214
SN - 1437-2096
ER -
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@article{2020_Lemcoff,
author = {N Gabriel Lemcoff and Noy B Nechmad},
title = {Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts},
journal = {Synlett},
year = {2020},
volume = {32},
publisher = {Thieme},
month = {aug},
url = {https://doi.org/10.1055/s-0040-1707231},
number = {03},
pages = {258--266},
doi = {10.1055/s-0040-1707231}
}
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Lemcoff, N. Gabriel, et al. “Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts.” Synlett, vol. 32, no. 03, Aug. 2020, pp. 258-266. https://doi.org/10.1055/s-0040-1707231.
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