The Electrocyclization of Heptatrienyl Anions
Publication type: Journal Article
Publication date: 2023-09-20
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
The thermal electrocyclization of heptatrienyl anions is reviewed. We begin with a succinct background on the importance of cycloheptane rings in complex molecules and a brief survey of approaches to their synthesis. We also review the fundamental aspects of this electrocyclization manifold, relying on the Woodward–Hoffmann rules for pericyclic chemistry. Then we survey the literature, covering the burst of discovery in the late 1960s and early 1970s, and the more sporadic reports in from the 1990s to the present day.
1 Introduction
2 The Electrocyclization of Heptatrienyl Anions
3 Discovery and Early Development (1964–1975)
4 Recent Developments (1996–2023)
5 Concluding Remarks
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7
Total citations:
7
Citations from 2025:
4
(57.14%)
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TY - JOUR
DO - 10.1055/s-0040-1720086
UR - https://doi.org/10.1055/s-0040-1720086
TI - The Electrocyclization of Heptatrienyl Anions
T2 - Synthesis
AU - Orellana, A
AU - Komijani, S
PY - 2023
DA - 2023/09/20
PB - Georg Thieme Verlag KG
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2023_Orellana,
author = {A Orellana and S Komijani},
title = {The Electrocyclization of Heptatrienyl Anions},
journal = {Synthesis},
year = {2023},
publisher = {Georg Thieme Verlag KG},
month = {sep},
url = {https://doi.org/10.1055/s-0040-1720086},
doi = {10.1055/s-0040-1720086}
}