Michael Addition of Nitroalkanes to Dimethyl Citraconate, with DBU as Base: An Unexpected, One-Pot Synthesis of Polyfunctionalized Carbonyl Derivatives
Publication type: Journal Article
Publication date: 2002-10-30
scimago Q3
wos Q3
SJR: 0.437
CiteScore: 3.3
Impact factor: 1.4
ISSN: 09365214, 14372096
Organic Chemistry
Abstract
Michael addition of nitroalkanes to dimethyl citraconate, with DBU as base, allows the one pot formation of keto diesters. The reaction proceeds through an equilibrium form of the acceptor, followed by Michael addition ofthe nitroalkane and then, in situ Nef conversion.
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Ballini R. et al. Michael Addition of Nitroalkanes to Dimethyl Citraconate, with DBU as Base: An Unexpected, One-Pot Synthesis of Polyfunctionalized Carbonyl Derivatives // Synlett. 2002. Vol. 10. pp. 1706-1708.
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Ballini R., Barboni L., Bosica G., Fiorini D., Gil M. I. Michael Addition of Nitroalkanes to Dimethyl Citraconate, with DBU as Base: An Unexpected, One-Pot Synthesis of Polyfunctionalized Carbonyl Derivatives // Synlett. 2002. Vol. 10. pp. 1706-1708.
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TY - JOUR
DO - 10.1055/s-2002-34209
UR - https://doi.org/10.1055/s-2002-34209
TI - Michael Addition of Nitroalkanes to Dimethyl Citraconate, with DBU as Base: An Unexpected, One-Pot Synthesis of Polyfunctionalized Carbonyl Derivatives
T2 - Synlett
AU - Ballini, Roberto
AU - Barboni, Luciano
AU - Bosica, Giovanna
AU - Fiorini, Dennis
AU - Gil, Maria I.
PY - 2002
DA - 2002/10/30
PB - Georg Thieme Verlag KG
SP - 1706-1708
IS - 10
SN - 0936-5214
SN - 1437-2096
ER -
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@article{2002_Ballini,
author = {Roberto Ballini and Luciano Barboni and Giovanna Bosica and Dennis Fiorini and Maria I. Gil},
title = {Michael Addition of Nitroalkanes to Dimethyl Citraconate, with DBU as Base: An Unexpected, One-Pot Synthesis of Polyfunctionalized Carbonyl Derivatives},
journal = {Synlett},
year = {2002},
publisher = {Georg Thieme Verlag KG},
month = {oct},
url = {https://doi.org/10.1055/s-2002-34209},
number = {10},
pages = {1706--1708},
doi = {10.1055/s-2002-34209}
}