6-Chloro- and 6-bromo-substituted steroids in the Suzuki-Miyaura cross-coupling reaction. A convenient route to potential aromatase inhibitors
Тип публикации: Journal Article
Дата публикации: 2006-01-25
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SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Краткое описание
Chlorine at an sp 2 -carbon in steroids has been shown to be reactive in Suzuki-Miyaura cross-coupling reactions with either Ni or Pd catalysts. The coupling of analogous 6-bromo derivatives has also been demonstrated to be applicable to a wider scope of substrates. The Suzuki-Miyaura arylation of 6-bromo-Δ 3 , 5 -steroid enol ethers with subsequent hydrolysis is a useful route to 6-arylated steroids bearing aryl at a saturated carbon.
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Lukashev N. V. et al. 6-Chloro- and 6-bromo-substituted steroids in the Suzuki-Miyaura cross-coupling reaction. A convenient route to potential aromatase inhibitors // Synthesis. 2006. Vol. 3. pp. 533-539.
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Lukashev N. V., Latyshev G. V., Donez P. A., Skryabin G. A., Beletskaya I. P. 6-Chloro- and 6-bromo-substituted steroids in the Suzuki-Miyaura cross-coupling reaction. A convenient route to potential aromatase inhibitors // Synthesis. 2006. Vol. 3. pp. 533-539.
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TY - JOUR
DO - 10.1055/s-2006-926270
UR - https://doi.org/10.1055/s-2006-926270
TI - 6-Chloro- and 6-bromo-substituted steroids in the Suzuki-Miyaura cross-coupling reaction. A convenient route to potential aromatase inhibitors
T2 - Synthesis
AU - Lukashev, Nikolay V
AU - Latyshev, Gennadij V
AU - Donez, Pavel A
AU - Skryabin, George A
AU - Beletskaya, Irina P.
PY - 2006
DA - 2006/01/25
PB - Georg Thieme Verlag KG
SP - 533-539
IS - 3
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2006_Lukashev,
author = {Nikolay V Lukashev and Gennadij V Latyshev and Pavel A Donez and George A Skryabin and Irina P. Beletskaya},
title = {6-Chloro- and 6-bromo-substituted steroids in the Suzuki-Miyaura cross-coupling reaction. A convenient route to potential aromatase inhibitors},
journal = {Synthesis},
year = {2006},
publisher = {Georg Thieme Verlag KG},
month = {jan},
url = {https://doi.org/10.1055/s-2006-926270},
number = {3},
pages = {533--539},
doi = {10.1055/s-2006-926270}
}