An Efficient CuI-Promoted Synthesis of Tri- and Tetrasubstituted Alkenes Using Organozinc Species
Publication type: Journal Article
Publication date: 2006-02-07
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
An efficient method for the synthesis of multifunctionalized alkenes has been developed. In the presence of 5 mol% Cul as catalyst, organozinc species CF 3 COOZnEt, CF 3 COOZnMe and CF 3 COOZnPh reacted with α,β-acetylenic ketones and aldehydes in one pot providing trisubstituted alkenes in high yields with stereoselectivity. The reaction with β-substituted-α,β-acetylenic ketones gave tetrasubstituted alkenes in good yields with Z-isomers as the major products.
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Total citations:
19
Citations from 2024:
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(5%)
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MLA
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GOST
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Xue S. et al. An Efficient CuI-Promoted Synthesis of Tri- and Tetrasubstituted Alkenes Using Organozinc Species // Synthesis. 2006. Vol. 2006. No. 04. pp. 666-674.
GOST all authors (up to 50)
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Xue S., He L., LIU Y., Han K., Guo Q. An Efficient CuI-Promoted Synthesis of Tri- and Tetrasubstituted Alkenes Using Organozinc Species // Synthesis. 2006. Vol. 2006. No. 04. pp. 666-674.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1055/s-2006-926299
UR - https://doi.org/10.1055/s-2006-926299
TI - An Efficient CuI-Promoted Synthesis of Tri- and Tetrasubstituted Alkenes Using Organozinc Species
T2 - Synthesis
AU - Xue, Song
AU - He, Lin
AU - LIU, YONGKANG
AU - Han, Kaizhen
AU - Guo, Qing-Xiang
PY - 2006
DA - 2006/02/07
PB - Georg Thieme Verlag KG
SP - 666-674
IS - 04
VL - 2006
SN - 0039-7881
SN - 1437-210X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2006_Xue,
author = {Song Xue and Lin He and YONGKANG LIU and Kaizhen Han and Qing-Xiang Guo},
title = {An Efficient CuI-Promoted Synthesis of Tri- and Tetrasubstituted Alkenes Using Organozinc Species},
journal = {Synthesis},
year = {2006},
volume = {2006},
publisher = {Georg Thieme Verlag KG},
month = {feb},
url = {https://doi.org/10.1055/s-2006-926299},
number = {04},
pages = {666--674},
doi = {10.1055/s-2006-926299}
}
Cite this
MLA
Copy
Xue, Song, et al. “An Efficient CuI-Promoted Synthesis of Tri- and Tetrasubstituted Alkenes Using Organozinc Species.” Synthesis, vol. 2006, no. 04, Feb. 2006, pp. 666-674. https://doi.org/10.1055/s-2006-926299.