Five- and Six-Membered Nickelacyclic Carboxylates as Reagents for the Facile Synthesis of δ-Ketocarboxylic Acids, Isocoumarins, and 1,3-Dicarbonyl Derivatives of Benzoic Acid
Тип публикации: Journal Article
Дата публикации: 2006-08-10
scimago Q2
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SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Краткое описание
The nickelacyclic carboxylates A and B reacted with α-halo ketones to form α,β-unsaturated δ-ketocarboxylic acids which were easily converted into pyranones or isocoumarins. In addition, reaction of the nickelacyclic acyl derivative C with α-halo ketones resulted in the formation of substituted 1,3-dicarbonyl compounds with a benzoic acid substituent in the 1-position. In these reactions, many functional groups were tolerated.
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Langer J., Gärtner M., Görls H. Five- and Six-Membered Nickelacyclic Carboxylates as Reagents for the Facile Synthesis of δ-Ketocarboxylic Acids, Isocoumarins, and 1,3-Dicarbonyl Derivatives of Benzoic Acid // Synthesis. 2006. Vol. 2006. No. 16. pp. 2697-2706.
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Langer J., Gärtner M., Görls H. Five- and Six-Membered Nickelacyclic Carboxylates as Reagents for the Facile Synthesis of δ-Ketocarboxylic Acids, Isocoumarins, and 1,3-Dicarbonyl Derivatives of Benzoic Acid // Synthesis. 2006. Vol. 2006. No. 16. pp. 2697-2706.
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TY - JOUR
DO - 10.1055/s-2006-942507
UR - https://doi.org/10.1055/s-2006-942507
TI - Five- and Six-Membered Nickelacyclic Carboxylates as Reagents for the Facile Synthesis of δ-Ketocarboxylic Acids, Isocoumarins, and 1,3-Dicarbonyl Derivatives of Benzoic Acid
T2 - Synthesis
AU - Langer, Jens
AU - Gärtner, Martin
AU - Görls, Helmar
PY - 2006
DA - 2006/08/10
PB - Georg Thieme Verlag KG
SP - 2697-2706
IS - 16
VL - 2006
SN - 0039-7881
SN - 1437-210X
ER -
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@article{2006_Langer,
author = {Jens Langer and Martin Gärtner and Helmar Görls},
title = {Five- and Six-Membered Nickelacyclic Carboxylates as Reagents for the Facile Synthesis of δ-Ketocarboxylic Acids, Isocoumarins, and 1,3-Dicarbonyl Derivatives of Benzoic Acid},
journal = {Synthesis},
year = {2006},
volume = {2006},
publisher = {Georg Thieme Verlag KG},
month = {aug},
url = {https://doi.org/10.1055/s-2006-942507},
number = {16},
pages = {2697--2706},
doi = {10.1055/s-2006-942507}
}
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Langer, Jens, et al. “Five- and Six-Membered Nickelacyclic Carboxylates as Reagents for the Facile Synthesis of δ-Ketocarboxylic Acids, Isocoumarins, and 1,3-Dicarbonyl Derivatives of Benzoic Acid.” Synthesis, vol. 2006, no. 16, Aug. 2006, pp. 2697-2706. https://doi.org/10.1055/s-2006-942507.