Mass Spectrometric Study of Ferrous Chloride Vapor
Publication type: Journal Article
Publication date: 1958-07-01
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Mass spectrometric studies of the vaporization process of ferrous chloride show that the major vapor species is monomeric FeCl2(g). A small concentration of Fe2Cl4(g) is present in the vapor at low temperatures. The ratio of dimer to monomer concentration increases rapidly with temperature showing that at the melting point of FeCl2(s), the equilibrium vapor consists of about 25% dimer. Thermodynamic treatment of ion current data yields for the reaction 2FeCl2(s)=Fe2Cl4(g),ΔH640∘K∘=56±3 kcal/mole of dimer and for the reactionFe2Cl4(g)=2FeCl2(g),ΔH640∘K∘=32±3 kcal/mole of dimer.
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Total citations:
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Citations from 2024:
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GOST
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Schoonmaker R. C., Porter R. F. Mass Spectrometric Study of Ferrous Chloride Vapor // Journal of Chemical Physics. 1958. Vol. 29. No. 1. pp. 116-120.
GOST all authors (up to 50)
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Schoonmaker R. C., Porter R. F. Mass Spectrometric Study of Ferrous Chloride Vapor // Journal of Chemical Physics. 1958. Vol. 29. No. 1. pp. 116-120.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/1.1744407
UR - https://doi.org/10.1063/1.1744407
TI - Mass Spectrometric Study of Ferrous Chloride Vapor
T2 - Journal of Chemical Physics
AU - Schoonmaker, Richard C
AU - Porter, Richard F
PY - 1958
DA - 1958/07/01
PB - AIP Publishing
SP - 116-120
IS - 1
VL - 29
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1958_Schoonmaker,
author = {Richard C Schoonmaker and Richard F Porter},
title = {Mass Spectrometric Study of Ferrous Chloride Vapor},
journal = {Journal of Chemical Physics},
year = {1958},
volume = {29},
publisher = {AIP Publishing},
month = {jul},
url = {https://doi.org/10.1063/1.1744407},
number = {1},
pages = {116--120},
doi = {10.1063/1.1744407}
}
Cite this
MLA
Copy
Schoonmaker, Richard C., and Richard F Porter. “Mass Spectrometric Study of Ferrous Chloride Vapor.” Journal of Chemical Physics, vol. 29, no. 1, Jul. 1958, pp. 116-120. https://doi.org/10.1063/1.1744407.