Journal of Physical and Chemical Reference Data, volume 47, issue 3, pages 33101

Elastic Constants, Bulk Modulus, and Compressibility of H2O Ice Ihfor the Temperature Range 50 K–273 K

J. J. NEUMEIER 1
1
 
Physics Department, Montana State University , Bozeman, Montana 59717-3840, USA
Publication typeJournal Article
Publication date2018-07-05
scimago Q1
wos Q1
SJR0.746
CiteScore6.9
Impact factor4.4
ISSN00472689, 15297845
General Chemistry
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Published elastic constant data for H2O ice in the Ih phase are compiled and evaluated. Fits of the five elastic constants for 50 ≤ T/K ≤ 273 are conducted to yield a reliable and convenient source for elastic constant values. Various elastic properties can be calculated from the elastic constants obtained herein. The elastic constants are used to determine the adiabatic bulk modulus BS for the same temperature range with an estimated uncertainty of less than 1.3%. Fitting those data yields an equation for BS that is extrapolated to provide values for 0 ≤ T/K < 50. The adiabatic compressibility KS, isothermal bulk modulus BT, and isothermal compressibility KT are calculated from BS. Comparisons are made to published data.Published elastic constant data for H2O ice in the Ih phase are compiled and evaluated. Fits of the five elastic constants for 50 ≤ T/K ≤ 273 are conducted to yield a reliable and convenient source for elastic constant values. Various elastic properties can be calculated from the elastic constants obtained herein. The elastic constants are used to determine the adiabatic bulk modulus BS for the same temperature range with an estimated uncertainty of less than 1.3%. Fitting those data yields an equation for BS that is extrapolated to provide values for 0 ≤ T/K < 50. The adiabatic compressibility KS, isothermal bulk modulus BT, and isothermal compressibility KT are calculated from BS. Comparisons are made to published data.
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