Journal of Chemical Physics

, том 54 , издание 11 , страницы 4769-4775

ESR Study of Radicals Formed by γ Irradiation of K₂PdCl₄ and (NH₄)₂PdCl₄ Single Crystals

Тип публикации: Journal Article

Дата публикации: 1971-06-01

AIP Publishing

Journal of Chemical Physics

scimago Q1

wos Q2

БС2

SJR: 0.819

CiteScore: 5.3

Impact factor: 3.1

ISSN: 00219606, 10897690

DOI: 10.1063/1.1674752

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Physical and Theoretical Chemistry

General Physics and Astronomy

Краткое описание

An X-band ESR study of γ-irradiated single crystals of K2PdCl4 and (NH4)2PdCl4 has been made at 77°K. Two radicals are observed, one of which is shown to be PdCl43− with a 4d9 configuration and dx2−y2 ground state; the complete g, A(105Pd) and A(35Cl) tensors have been reported for this species. The second radical is believed to be PdCl52−, and its ESR parameters are presented and discussed.

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Krigas T., Rogers M. T. ESR Study of Radicals Formed by γ Irradiation of K2PdCl4 and (NH4)2PdCl4 Single Crystals // Journal of Chemical Physics. 1971. Vol. 54. No. 11. pp. 4769-4775.

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Krigas T., Rogers M. T. ESR Study of Radicals Formed by γ Irradiation of K2PdCl4 and (NH4)2PdCl4 Single Crystals // Journal of Chemical Physics. 1971. Vol. 54. No. 11. pp. 4769-4775.

RIS |

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TY - JOUR

DO - 10.1063/1.1674752

UR - https://doi.org/10.1063/1.1674752

TI - ESR Study of Radicals Formed by γ Irradiation of K2PdCl4 and (NH4)2PdCl4 Single Crystals

T2 - Journal of Chemical Physics

AU - Krigas, Thomas

AU - Rogers, Max T.

PY - 1971

DA - 1971/06/01

PB - AIP Publishing

SP - 4769-4775

IS - 11

VL - 54

SN - 0021-9606

SN - 1089-7690

ER -

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@article{1971_Krigas,

author = {Thomas Krigas and Max T. Rogers},

title = {ESR Study of Radicals Formed by γ Irradiation of K2PdCl4 and (NH4)2PdCl4 Single Crystals},

journal = {Journal of Chemical Physics},

year = {1971},

volume = {54},

publisher = {AIP Publishing},

month = {jun},

url = {https://doi.org/10.1063/1.1674752},

number = {11},

pages = {4769--4775},

doi = {10.1063/1.1674752}

}

MLA

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MLA Скопировать

Krigas, Thomas, and Max T. Rogers. “ESR Study of Radicals Formed by γ Irradiation of K2PdCl4 and (NH4)2PdCl4 Single Crystals.” Journal of Chemical Physics, vol. 54, no. 11, Jun. 1971, pp. 4769-4775. https://doi.org/10.1063/1.1674752.

Издатель

AIP Publishing

Журнал

Journal of Chemical Physics

scimago Q1

wos Q2

БС2

SJR

0.819

CiteScore

5.3

Impact factor

3.1

ISSN

00219606 (Print)

10897690 (Electronic)