The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°C
Тип публикации: Journal Article
Дата публикации: 1953-04-01
scimago Q1
wos Q2
БС2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
A technique has been developed for handling the extremely reactive interhalogen compounds which makes it possible to investigate their structures by x-ray diffraction at low temperatures. As the first step in a program of study of the interhalogen group the crystal structure of chlorine trifluoride has been determined at −120°C. The chlorine trifluoride molecule is planar with the point group symmetry mm. The Cl atom is bonded to one F atom at 1.621A and to two F atoms at 1.716A. The F–Cl–F bond angle is 86°59′. In the succeeding pages of this journal, a parallel investigation of the vapor phase by microwave spectroscopy is presented by Dr. D. F. Smith. The molecular configuration is identical in the two cases.
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Burbank R. D., Bensey F. N. The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°C // Journal of Chemical Physics. 1953. Vol. 21. No. 4. pp. 602-608.
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Burbank R. D., Bensey F. N. The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°C // Journal of Chemical Physics. 1953. Vol. 21. No. 4. pp. 602-608.
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TY - JOUR
DO - 10.1063/1.1698975
UR - https://doi.org/10.1063/1.1698975
TI - The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°C
T2 - Journal of Chemical Physics
AU - Burbank, Robinson D
AU - Bensey, Frank N
PY - 1953
DA - 1953/04/01
PB - AIP Publishing
SP - 602-608
IS - 4
VL - 21
SN - 0021-9606
SN - 1089-7690
ER -
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@article{1953_Burbank,
author = {Robinson D Burbank and Frank N Bensey},
title = {The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°C},
journal = {Journal of Chemical Physics},
year = {1953},
volume = {21},
publisher = {AIP Publishing},
month = {apr},
url = {https://doi.org/10.1063/1.1698975},
number = {4},
pages = {602--608},
doi = {10.1063/1.1698975}
}
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MLA
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Burbank, Robinson D., and Frank N Bensey. “The Structures of the Interhalogen Compounds. I. Chlorine Trifluoride at −120°C.” Journal of Chemical Physics, vol. 21, no. 4, Apr. 1953, pp. 602-608. https://doi.org/10.1063/1.1698975.