Journal of Chemical Physics

, volume 20 , issue 10 , pages 1526-1532

Cooperative Orientation Effects in Solutions

J A BARKER ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Division of Industrial Chemistry, C.S.I.R.O., Melbourne, Australia |

Publication type: Journal Article

Publication date: 1952-10-01

AIP Publishing

Journal of Chemical Physics

scimago Q1

wos Q2

SJR: 0.819

CiteScore: 5.3

Impact factor: 3.1

ISSN: 00219606, 10897690

DOI: 10.1063/1.1700209

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Physical and Theoretical Chemistry

General Physics and Astronomy

Abstract

A general theoretical method for evaluating the effect on thermodynamic properties of cooperative orientation in solutions is developed. The theory is applied to the systems methanol+benzene, methanol carbon tetrachloride, and chloroform+ethanol. Theoretical curves for excess free energy of mixing, heat of mixing, and excess entropy of mixing as functions of composition are presented and are in reasonable quantitative agreement with experimental values for the first two systems and qualitatively similar to the experimental curves for the third. It is concluded that the method provides a useful approach to the theory of solutions of associated liquids in general.

Found

2 citations

Selyutin Artem

PhD in Chemistry

76 publications, 438 citations, 1 review

h-index: 12

Saint Petersburg State University

Research interests

Inorganic Chemistry

1 citation

Simonenko Nikolay

🥼 🤝

PhD in Chemistry

262 publications, 3 508 citations

h-index: 32

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Alternative energy

Electronics

High temperature materials

Optics

Printing technologies

Sensorics

Synthesis of nanomaterials

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GOST |

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GOST Copy

BARKER J. A. Cooperative Orientation Effects in Solutions // Journal of Chemical Physics. 1952. Vol. 20. No. 10. pp. 1526-1532.

GOST all authors (up to 50) Copy

BARKER J. A. Cooperative Orientation Effects in Solutions // Journal of Chemical Physics. 1952. Vol. 20. No. 10. pp. 1526-1532.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1063/1.1700209

UR - https://doi.org/10.1063/1.1700209

TI - Cooperative Orientation Effects in Solutions

T2 - Journal of Chemical Physics

AU - BARKER, J A

PY - 1952

DA - 1952/10/01

PB - AIP Publishing

SP - 1526-1532

IS - 10

VL - 20

SN - 0021-9606

SN - 1089-7690

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{1952_BARKER,

author = {J A BARKER},

title = {Cooperative Orientation Effects in Solutions},

journal = {Journal of Chemical Physics},

year = {1952},

volume = {20},

publisher = {AIP Publishing},

month = {oct},

url = {https://doi.org/10.1063/1.1700209},

number = {10},

pages = {1526--1532},

doi = {10.1063/1.1700209}

}

MLA

Cite this

MLA Copy

BARKER, J. A.. “Cooperative Orientation Effects in Solutions.” Journal of Chemical Physics, vol. 20, no. 10, Oct. 1952, pp. 1526-1532. https://doi.org/10.1063/1.1700209.

Publisher

AIP Publishing

Journal

Journal of Chemical Physics

scimago Q1

wos Q2

SJR

0.819

CiteScore

5.3

Impact factor

3.1

ISSN

00219606 (Print)

10897690 (Electronic)