Carbon‐Hydrogen‐Acetylene Equilibrium at High Temperatures
1
Linde Company, Division of Union Carbide Corporation, Speedway Laboratories, Indianapolis, Indiana
|
Publication type: Journal Article
Publication date: 1959-07-01
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The concentration of acetylene in equilibrium with carbon and hydrogen at temperatures up to 3000°K has been measured experimentally using water-cooled quenching probes in a carbon tube furnace. Previous calculations of the thermodynamic properties of acetylene have been extended to cover this temperature range. Also, the effects of free radical species present at these temperatures were estimated. The only ones deemed important in the temperature range of this investigation were H and C2H; an estimate was made of the free energy of C2H to predict its effect on the composition of the quenched gas samples from the furnace. The predicted quenched gas compositions are in good agreement with the experimental measurements.
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Metrics
31
Total citations:
31
Citations from 2025:
2
(6.66%)
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MLA
Cite this
GOST
Copy
Plooster M. N., Reed T. B. Carbon‐Hydrogen‐Acetylene Equilibrium at High Temperatures // Journal of Chemical Physics. 1959. Vol. 31. No. 1. pp. 66-72.
GOST all authors (up to 50)
Copy
Plooster M. N., Reed T. B. Carbon‐Hydrogen‐Acetylene Equilibrium at High Temperatures // Journal of Chemical Physics. 1959. Vol. 31. No. 1. pp. 66-72.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/1.1730338
UR - https://doi.org/10.1063/1.1730338
TI - Carbon‐Hydrogen‐Acetylene Equilibrium at High Temperatures
T2 - Journal of Chemical Physics
AU - Plooster, Myron N.
AU - Reed, Thomas B
PY - 1959
DA - 1959/07/01
PB - AIP Publishing
SP - 66-72
IS - 1
VL - 31
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1959_Plooster,
author = {Myron N. Plooster and Thomas B Reed},
title = {Carbon‐Hydrogen‐Acetylene Equilibrium at High Temperatures},
journal = {Journal of Chemical Physics},
year = {1959},
volume = {31},
publisher = {AIP Publishing},
month = {jul},
url = {https://doi.org/10.1063/1.1730338},
number = {1},
pages = {66--72},
doi = {10.1063/1.1730338}
}
Cite this
MLA
Copy
Plooster, Myron N., and Thomas B Reed. “Carbon‐Hydrogen‐Acetylene Equilibrium at High Temperatures.” Journal of Chemical Physics, vol. 31, no. 1, Jul. 1959, pp. 66-72. https://doi.org/10.1063/1.1730338.