Applied Physics Letters

, volume 87 , issue 24 , pages 244102

Complexation of pyrrolidinofullerenes and zinc-phthalocyanine in a bilayer organic solar cell structure

Robert Koeppe ¹

N. Serdar Sariciftci ¹

Pavel A. Troshin ²

Rimma N. Lyubovskaya ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Linz Institute for Organic Solar Cells (LIOS) , Altenbergerstrasse 69, A-4040 Linz, Austria |

Institute of Problems of Chemical Physics of RAS , Chernogolovka, Moscow Region 142432, Russia |

Publication type: Journal Article

Publication date: 2005-12-06

AIP Publishing

Applied Physics Letters

scimago Q1

wos Q2

SJR: 0.896

CiteScore: 6.1

Impact factor: 3.6

ISSN: 00036951, 10773118

DOI: 10.1063/1.2146070

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Physics and Astronomy (miscellaneous)

Abstract

Bilayer organic solar cells were prepared using zinc-phthalocyanine (ZnPc) and a novel, highly soluble pyrollidinofullerene bearing three chelating pyridyl groups (PyF). The formation of supramolecular complexes between the two compounds is indicated by a significantly increased solubility of ZnPc in dichloromethane upon addition of the PyF. Spin-coating a film of PyF on a vacuum-evaporated film of ZnPc results in a solar cell yielding short circuit current (Isc) densities of 3mA∕cm2 and open-circuit voltages (Voc) of about 0.4V under 100mW∕cm2 simulated AM1.5 illumination. Solar cells prepared by substituting the PyF with a fullerene derivative forming no complexes with ZnPc show significantly lower photovoltaic conversion efficiencies.

Found

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Faraonov Maxim

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PhD in Chemistry

59 publications, 423 citations, 2 reviews

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Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

1 citation

Ilichev Vasily

PhD in Chemistry

87 publications, 863 citations, 1 review

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G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Ludovico Valli

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University of Salento

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Koeppe R. et al. Complexation of pyrrolidinofullerenes and zinc-phthalocyanine in a bilayer organic solar cell structure // Applied Physics Letters. 2005. Vol. 87. No. 24. p. 244102.

GOST all authors (up to 50) Copy

Koeppe R., Sariciftci N. S., Troshin P. A., Lyubovskaya R. N. Complexation of pyrrolidinofullerenes and zinc-phthalocyanine in a bilayer organic solar cell structure // Applied Physics Letters. 2005. Vol. 87. No. 24. p. 244102.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1063/1.2146070

UR - https://doi.org/10.1063/1.2146070

TI - Complexation of pyrrolidinofullerenes and zinc-phthalocyanine in a bilayer organic solar cell structure

T2 - Applied Physics Letters

AU - Koeppe, Robert

AU - Sariciftci, N. Serdar

AU - Troshin, Pavel A.

AU - Lyubovskaya, Rimma N.

PY - 2005

DA - 2005/12/06

PB - AIP Publishing

SP - 244102

IS - 24

VL - 87

SN - 0003-6951

SN - 1077-3118

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2005_Koeppe,

author = {Robert Koeppe and N. Serdar Sariciftci and Pavel A. Troshin and Rimma N. Lyubovskaya},

title = {Complexation of pyrrolidinofullerenes and zinc-phthalocyanine in a bilayer organic solar cell structure},

journal = {Applied Physics Letters},

year = {2005},

volume = {87},

publisher = {AIP Publishing},

month = {dec},

url = {https://doi.org/10.1063/1.2146070},

number = {24},

pages = {244102},

doi = {10.1063/1.2146070}

}

MLA

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MLA Copy

Koeppe, Robert, et al. “Complexation of pyrrolidinofullerenes and zinc-phthalocyanine in a bilayer organic solar cell structure.” Applied Physics Letters, vol. 87, no. 24, Dec. 2005, p. 244102. https://doi.org/10.1063/1.2146070.