Journal of Chemical Physics, volume 129, issue 8, pages 84701

State-resolved studies of biexcitons and surface trapping dynamics in semiconductor quantum dots

Samuel L. Sewall 1
Ryan R. Cooney 1
Kevin E H Anderson 1
Eva A. Dias 1
D. M. Sagar 1
Publication typeJournal Article
Publication date2008-08-22
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.4
ISSN00219606, 10897690
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract

Biexcitons in strongly confined, colloidal CdSe quantum dots were investigated with excitonic state selectivity combined with 10 fs temporal precision. Within the first 50 fs, the first excited state of the biexciton was observed. By 100 ps, mixed character biexcitons were observed, comprised of a core exciton and a surface trapped exciton. The size dependence of the biexciton binding energies is reported for these specific biexcitons. Analysis of the spectral signatures of each biexcitonic state yields a quantitative measure of enhanced excited state trapping rates at the surface of the quantum dots. By comparing the biexcitonic signals to the state-filling signals, we show that it is primarily the holes which are trapped at the interface on the 100 ps time scale.

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GOST Copy
Sewall S. L. et al. State-resolved studies of biexcitons and surface trapping dynamics in semiconductor quantum dots // Journal of Chemical Physics. 2008. Vol. 129. No. 8. p. 84701.
GOST all authors (up to 50) Copy
Sewall S. L., Cooney R. R., Anderson K. E. H., Dias E. A., Sagar D. M., Kambhampati P. State-resolved studies of biexcitons and surface trapping dynamics in semiconductor quantum dots // Journal of Chemical Physics. 2008. Vol. 129. No. 8. p. 84701.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1063/1.2971181
UR - https://doi.org/10.1063/1.2971181
TI - State-resolved studies of biexcitons and surface trapping dynamics in semiconductor quantum dots
T2 - Journal of Chemical Physics
AU - Sewall, Samuel L.
AU - Cooney, Ryan R.
AU - Anderson, Kevin E H
AU - Dias, Eva A.
AU - Sagar, D. M.
AU - Kambhampati, Patanjali
PY - 2008
DA - 2008/08/22 00:00:00
PB - American Institute of Physics (AIP)
SP - 84701
IS - 8
VL - 129
SN - 0021-9606
SN - 1089-7690
ER -
BibTex |
Cite this
BibTex Copy
@article{2008_Sewall,
author = {Samuel L. Sewall and Ryan R. Cooney and Kevin E H Anderson and Eva A. Dias and D. M. Sagar and Patanjali Kambhampati},
title = {State-resolved studies of biexcitons and surface trapping dynamics in semiconductor quantum dots},
journal = {Journal of Chemical Physics},
year = {2008},
volume = {129},
publisher = {American Institute of Physics (AIP)},
month = {aug},
url = {https://doi.org/10.1063/1.2971181},
number = {8},
pages = {84701},
doi = {10.1063/1.2971181}
}
MLA
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MLA Copy
Sewall, Samuel L., et al. “State-resolved studies of biexcitons and surface trapping dynamics in semiconductor quantum dots.” Journal of Chemical Physics, vol. 129, no. 8, Aug. 2008, p. 84701. https://doi.org/10.1063/1.2971181.
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