Direct visualization of the H-Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra
Vladimir I Feldman
1, 2
,
Alexey V Kobzarenko
1
,
Irina A Baranova
1
,
Fedor F Sukhov
1
,
Ehud Tsivion
3
,
R. Benny Gerber
3, 4
4
University of California 4 Department of Chemistry, , Irvine, California 92697-2025, USA
|
Publication type: Journal Article
Publication date: 2009-10-16
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
PubMed ID:
20568838
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
IR spectra of xenon hydrides (HXeCCH, HXeCC, and HXeH) obtained from different xenon isotopes (X129e and X136e) exhibit a small but detectable and reproducible isotopic shift in the absorptions assigned to H–Xe stretching (by 0.17–0.38 cm−1). To our knowledge, it is the first direct experimental evidence for the H–Xe bond in HXeY type compounds. The shift magnitude is in good agreement with quantum-chemical calculations.
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Total citations:
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Citations from 2024:
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GOST
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Feldman V. I. et al. Direct visualization of the H-Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra // Journal of Chemical Physics. 2009. Vol. 131. No. 15. p. 151101.
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Feldman V. I., Kobzarenko A. V., Baranova I. A., Danchenko A. V., Sukhov F. F., Tsivion E., Gerber R. B. Direct visualization of the H-Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra // Journal of Chemical Physics. 2009. Vol. 131. No. 15. p. 151101.
Cite this
RIS
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TY - JOUR
DO - 10.1063/1.3250426
UR - https://pubs.aip.org/jcp/article/131/15/151101/316790/Direct-visualization-of-the-H-Xe-bond-in-xenon
TI - Direct visualization of the H-Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra
T2 - Journal of Chemical Physics
AU - Feldman, Vladimir I
AU - Kobzarenko, Alexey V
AU - Baranova, Irina A
AU - Danchenko, Alexander V
AU - Sukhov, Fedor F
AU - Tsivion, Ehud
AU - Gerber, R. Benny
PY - 2009
DA - 2009/10/16
PB - AIP Publishing
SP - 151101
IS - 15
VL - 131
PMID - 20568838
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Feldman,
author = {Vladimir I Feldman and Alexey V Kobzarenko and Irina A Baranova and Alexander V Danchenko and Fedor F Sukhov and Ehud Tsivion and R. Benny Gerber},
title = {Direct visualization of the H-Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra},
journal = {Journal of Chemical Physics},
year = {2009},
volume = {131},
publisher = {AIP Publishing},
month = {oct},
url = {https://pubs.aip.org/jcp/article/131/15/151101/316790/Direct-visualization-of-the-H-Xe-bond-in-xenon},
number = {15},
pages = {151101},
doi = {10.1063/1.3250426}
}
Cite this
MLA
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Feldman, Vladimir I., et al. “Direct visualization of the H-Xe bond in xenon hydrides: Xenon isotopic shift in the IR spectra.” Journal of Chemical Physics, vol. 131, no. 15, Oct. 2009, p. 151101. https://pubs.aip.org/jcp/article/131/15/151101/316790/Direct-visualization-of-the-H-Xe-bond-in-xenon.