Journal of Applied Physics, volume 61, issue 12, pages 5399-5409
Quantum confinement effects of semiconducting microcrystallites in glass
1
Research and Development Division, Corning Glass Works, Corning, New York 14831
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Publication type: Journal Article
Publication date: 1987-06-15
Journal:
Journal of Applied Physics
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 3.2
ISSN: 00218979, 10897550
DOI:
10.1063/1.338280
General Physics and Astronomy
Abstract
The optical properties of glasses containing a small amount of thermally developed CdSexS1−x microcrystalline phase are studied with emphasis on quantum confinement effects exhibited at small crystallite size. Optical absorption, photoluminescence, x-ray diffraction, and transmission electron microscopy are used to examine microcrystallites as a function of composition and development. Results are presented for a series of commercially available CorningR filter glasses with a selenium mole fraction in the range 0.28≤x≤0.74, as well as for several experimental glasses in which the average microcrystallite diameters range from 30 to 80 Å. Optical effects observed in the experimental glasses that are due to electron and hole confinement are not present in the filter glasses considered; variations in optical properties of the filters are due to changes in stoichiometry of the CdSexS1−x mixed anion system. A brief discussion of other microcrystalline phases in glass is also presented. These microcrystallites show room-temperature optical absorption structure analogous to bulk crystal excitons; the temperature dependence of this structure is contrasted with that resulting from quantum confinement in CdSexS1−x glasses.
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Borrelli N. F. et al. Quantum confinement effects of semiconducting microcrystallites in glass // Journal of Applied Physics. 1987. Vol. 61. No. 12. pp. 5399-5409.
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Borrelli N. F., Hall D. W., Holland H. J., Smith D. Quantum confinement effects of semiconducting microcrystallites in glass // Journal of Applied Physics. 1987. Vol. 61. No. 12. pp. 5399-5409.
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TY - JOUR
DO - 10.1063/1.338280
UR - https://doi.org/10.1063/1.338280
TI - Quantum confinement effects of semiconducting microcrystallites in glass
T2 - Journal of Applied Physics
AU - Borrelli, N. F.
AU - Hall, D. W.
AU - Holland, H. J.
AU - Smith, D.W.
PY - 1987
DA - 1987/06/15 00:00:00
PB - American Institute of Physics (AIP)
SP - 5399-5409
IS - 12
VL - 61
SN - 0021-8979
SN - 1089-7550
ER -
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@article{1987_Borrelli,
author = {N. F. Borrelli and D. W. Hall and H. J. Holland and D.W. Smith},
title = {Quantum confinement effects of semiconducting microcrystallites in glass},
journal = {Journal of Applied Physics},
year = {1987},
volume = {61},
publisher = {American Institute of Physics (AIP)},
month = {jun},
url = {https://doi.org/10.1063/1.338280},
number = {12},
pages = {5399--5409},
doi = {10.1063/1.338280}
}
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MLA
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Borrelli, N. F., et al. “Quantum confinement effects of semiconducting microcrystallites in glass.” Journal of Applied Physics, vol. 61, no. 12, Jun. 1987, pp. 5399-5409. https://doi.org/10.1063/1.338280.