Applied Physics Letters, volume 97, issue 3, pages 31916

Anharmonicity in LiBH4–LiI induced by anion exchange and temperature

Publication typeJournal Article
Publication date2010-07-19
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor4
ISSN00036951, 10773118
Physics and Astronomy (miscellaneous)
Abstract

The feasibility of spatially resolved Raman spectroscopy probing diffusion multiples as a high-throughput method to study phase transformations in Li-ion conductors is demonstrated. The method is applied to the pseudobinary LiBH4–LiI system, which shows high Li-ion conductivity in the HT-phase of LiBH4. The vibrational properties measured as a function of composition and temperature corroborate the formation of a solid solution of Li(BH4)1−cIc over nearly the entire phase diagram (0<c≤0.8±0.2). The results shed light on anharmonic effects responsible for the structural phase transformation in this system.

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GOST Copy
Borgschulte A. et al. Anharmonicity in LiBH4–LiI induced by anion exchange and temperature // Applied Physics Letters. 2010. Vol. 97. No. 3. p. 31916.
GOST all authors (up to 50) Copy
Borgschulte A., Gremaud R., Kato S., Stadie N. P., Remhof A., Züttel A., Matsuo M., Orimo S. I. Anharmonicity in LiBH4–LiI induced by anion exchange and temperature // Applied Physics Letters. 2010. Vol. 97. No. 3. p. 31916.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1063/1.3467260
UR - https://doi.org/10.1063/1.3467260
TI - Anharmonicity in LiBH4–LiI induced by anion exchange and temperature
T2 - Applied Physics Letters
AU - Borgschulte, A
AU - Gremaud, R.
AU - Kato, S.
AU - Stadie, N P
AU - Remhof, A.
AU - Züttel, A
AU - Matsuo, M.
AU - Orimo, S I
PY - 2010
DA - 2010/07/19 00:00:00
PB - American Institute of Physics (AIP)
SP - 31916
IS - 3
VL - 97
SN - 0003-6951
SN - 1077-3118
ER -
BibTex |
Cite this
BibTex Copy
@article{2010_Borgschulte,
author = {A Borgschulte and R. Gremaud and S. Kato and N P Stadie and A. Remhof and A Züttel and M. Matsuo and S I Orimo},
title = {Anharmonicity in LiBH4–LiI induced by anion exchange and temperature},
journal = {Applied Physics Letters},
year = {2010},
volume = {97},
publisher = {American Institute of Physics (AIP)},
month = {jul},
url = {https://doi.org/10.1063/1.3467260},
number = {3},
pages = {31916},
doi = {10.1063/1.3467260}
}
MLA
Cite this
MLA Copy
Borgschulte, A., et al. “Anharmonicity in LiBH4–LiI induced by anion exchange and temperature.” Applied Physics Letters, vol. 97, no. 3, Jul. 2010, p. 31916. https://doi.org/10.1063/1.3467260.
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