Anharmonicity in LiBH4–LiI induced by anion exchange and temperature
A Borgschulte
1
,
R. Gremaud
1
,
S. Kato
1
,
N P Stadie
1
,
A. Remhof
1
,
A Züttel
1
,
M. Matsuo
2
,
S I Orimo
2
Publication type: Journal Article
Publication date: 2010-07-19
scimago Q1
wos Q2
SJR: 0.896
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00036951, 10773118
Physics and Astronomy (miscellaneous)
Abstract
The feasibility of spatially resolved Raman spectroscopy probing diffusion multiples as a high-throughput method to study phase transformations in Li-ion conductors is demonstrated. The method is applied to the pseudobinary LiBH4–LiI system, which shows high Li-ion conductivity in the HT-phase of LiBH4. The vibrational properties measured as a function of composition and temperature corroborate the formation of a solid solution of Li(BH4)1−cIc over nearly the entire phase diagram (0<c≤0.8±0.2). The results shed light on anharmonic effects responsible for the structural phase transformation in this system.
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Total citations:
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Citations from 2024:
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GOST
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Borgschulte A. et al. Anharmonicity in LiBH4–LiI induced by anion exchange and temperature // Applied Physics Letters. 2010. Vol. 97. No. 3. p. 31916.
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Borgschulte A., Gremaud R., Kato S., Stadie N. P., Remhof A., Züttel A., Matsuo M., Orimo S. I. Anharmonicity in LiBH4–LiI induced by anion exchange and temperature // Applied Physics Letters. 2010. Vol. 97. No. 3. p. 31916.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/1.3467260
UR - https://doi.org/10.1063/1.3467260
TI - Anharmonicity in LiBH4–LiI induced by anion exchange and temperature
T2 - Applied Physics Letters
AU - Borgschulte, A
AU - Gremaud, R.
AU - Kato, S.
AU - Stadie, N P
AU - Remhof, A.
AU - Züttel, A
AU - Matsuo, M.
AU - Orimo, S I
PY - 2010
DA - 2010/07/19
PB - AIP Publishing
SP - 31916
IS - 3
VL - 97
SN - 0003-6951
SN - 1077-3118
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Borgschulte,
author = {A Borgschulte and R. Gremaud and S. Kato and N P Stadie and A. Remhof and A Züttel and M. Matsuo and S I Orimo},
title = {Anharmonicity in LiBH4–LiI induced by anion exchange and temperature},
journal = {Applied Physics Letters},
year = {2010},
volume = {97},
publisher = {AIP Publishing},
month = {jul},
url = {https://doi.org/10.1063/1.3467260},
number = {3},
pages = {31916},
doi = {10.1063/1.3467260}
}
Cite this
MLA
Copy
Borgschulte, A., et al. “Anharmonicity in LiBH4–LiI induced by anion exchange and temperature.” Applied Physics Letters, vol. 97, no. 3, Jul. 2010, p. 31916. https://doi.org/10.1063/1.3467260.