Communication: Stabilization of radical anions with weakly bound electron in condensed media: A case study of diacetonyl radical anion
Publication type: Journal Article
Publication date: 2011-09-12
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
PubMed ID:
21932869
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The radical anion resulting from electron capture by diacetonyl molecule has been characterized by EPR and optical absorption spectroscopy in glassy ether matrices at 77 K. In non-polar alkane glasses this species was not observed under the same conditions, which confirms the crucial role of matrix interactions in stabilizing this species. Calculations at the MP2 level show the vertical detachment energy to increase gradually from roughly zero for a bare anion to ∼1 eV for the complex involving six ether molecules.
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Saenko E. V. et al. Communication: Stabilization of radical anions with weakly bound electron in condensed media: A case study of diacetonyl radical anion // Journal of Chemical Physics. 2011. Vol. 135. No. 10. p. 101103.
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Saenko E. V., Laikov D. N., Baranova I. A., Feldman V. I. Communication: Stabilization of radical anions with weakly bound electron in condensed media: A case study of diacetonyl radical anion // Journal of Chemical Physics. 2011. Vol. 135. No. 10. p. 101103.
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RIS
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TY - JOUR
DO - 10.1063/1.3638690
UR - https://pubs.aip.org/jcp/article/135/10/101103/983373/Communication-Stabilization-of-radical-anions-with
TI - Communication: Stabilization of radical anions with weakly bound electron in condensed media: A case study of diacetonyl radical anion
T2 - Journal of Chemical Physics
AU - Saenko, Elizaveta V
AU - Laikov, Dimitri N
AU - Baranova, Irina A
AU - Feldman, Vladimir I
PY - 2011
DA - 2011/09/12
PB - AIP Publishing
SP - 101103
IS - 10
VL - 135
PMID - 21932869
SN - 0021-9606
SN - 1089-7690
ER -
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BibTex (up to 50 authors)
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@article{2011_Saenko,
author = {Elizaveta V Saenko and Dimitri N Laikov and Irina A Baranova and Vladimir I Feldman},
title = {Communication: Stabilization of radical anions with weakly bound electron in condensed media: A case study of diacetonyl radical anion},
journal = {Journal of Chemical Physics},
year = {2011},
volume = {135},
publisher = {AIP Publishing},
month = {sep},
url = {https://pubs.aip.org/jcp/article/135/10/101103/983373/Communication-Stabilization-of-radical-anions-with},
number = {10},
pages = {101103},
doi = {10.1063/1.3638690}
}
Cite this
MLA
Copy
Saenko, Elizaveta V., et al. “Communication: Stabilization of radical anions with weakly bound electron in condensed media: A case study of diacetonyl radical anion.” Journal of Chemical Physics, vol. 135, no. 10, Sep. 2011, p. 101103. https://pubs.aip.org/jcp/article/135/10/101103/983373/Communication-Stabilization-of-radical-anions-with.